Bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate

The title compound, (C(4)H(14)N(2))(2)[Mo(2)O(4)F(6)]·H(2)O, was obtained by solvothermal reaction at 443 K for 72 h from a mixture of MoO(3), HF, 1,4-diamino­butane (dab), water and ethyl­ene glycol. The structure consists of [Mo(2)O(4)F(6)](4−) anionic dimers containing strongly distorted MoO(3)F(...

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Autores principales: Lhoste, J., Hemon-Ribaud, A., Maisonneuve, V., Jobic, S., Bujoli-Doeuff, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588766/
https://www.ncbi.nlm.nih.gov/pubmed/23468731
http://dx.doi.org/10.1107/S1600536812046892
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author Lhoste, J.
Hemon-Ribaud, A.
Maisonneuve, V.
Jobic, S.
Bujoli-Doeuff, M.
author_facet Lhoste, J.
Hemon-Ribaud, A.
Maisonneuve, V.
Jobic, S.
Bujoli-Doeuff, M.
author_sort Lhoste, J.
collection PubMed
description The title compound, (C(4)H(14)N(2))(2)[Mo(2)O(4)F(6)]·H(2)O, was obtained by solvothermal reaction at 443 K for 72 h from a mixture of MoO(3), HF, 1,4-diamino­butane (dab), water and ethyl­ene glycol. The structure consists of [Mo(2)O(4)F(6)](4−) anionic dimers containing strongly distorted MoO(3)F(3) octa­hedra (with twofold symmetry), diprotonated dab cations and water mol­ecules (twofold symmetry) in the ratio 1:2:1. The cohesion of the three-dimensional structure is ensured through N—H⋯O, N—H⋯F and O—H⋯F inter­actions.
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spelling pubmed-35887662013-03-06 Bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate Lhoste, J. Hemon-Ribaud, A. Maisonneuve, V. Jobic, S. Bujoli-Doeuff, M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(4)H(14)N(2))(2)[Mo(2)O(4)F(6)]·H(2)O, was obtained by solvothermal reaction at 443 K for 72 h from a mixture of MoO(3), HF, 1,4-diamino­butane (dab), water and ethyl­ene glycol. The structure consists of [Mo(2)O(4)F(6)](4−) anionic dimers containing strongly distorted MoO(3)F(3) octa­hedra (with twofold symmetry), diprotonated dab cations and water mol­ecules (twofold symmetry) in the ratio 1:2:1. The cohesion of the three-dimensional structure is ensured through N—H⋯O, N—H⋯F and O—H⋯F inter­actions. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588766/ /pubmed/23468731 http://dx.doi.org/10.1107/S1600536812046892 Text en © Lhoste et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lhoste, J.
Hemon-Ribaud, A.
Maisonneuve, V.
Jobic, S.
Bujoli-Doeuff, M.
Bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate
title Bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate
title_full Bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate
title_fullStr Bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate
title_full_unstemmed Bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate
title_short Bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate
title_sort bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(v)] monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588766/
https://www.ncbi.nlm.nih.gov/pubmed/23468731
http://dx.doi.org/10.1107/S1600536812046892
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AT maisonneuvev bisbutane14diammoniumdimoxidobistrifluoridooxidomolybdatevmonohydrate
AT jobics bisbutane14diammoniumdimoxidobistrifluoridooxidomolybdatevmonohydrate
AT bujolidoeuffm bisbutane14diammoniumdimoxidobistrifluoridooxidomolybdatevmonohydrate

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