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Chlorido(4-methylpyridin-2-amine-κN (1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II)

In the title complex, [Cu(C(13)H(11)N(2)O)Cl(C(6)H(8)N(2))], the Cu(II) atom adopts a distorted tetra­hedral geometry being coordinated by the phenolic O atom and the azomethine N atom of the Schiff base ligand N-salicyl­idene 2-amino­pyridine, and by the 2-amino­pyridine N atom and a Cl atom. The p...

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Detalles Bibliográficos
Autores principales: Bhagyaraju, Bussa, Sambasiva Rao, P., Swu, Toka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588768/
https://www.ncbi.nlm.nih.gov/pubmed/23468733
http://dx.doi.org/10.1107/S1600536812047198
Descripción
Sumario:In the title complex, [Cu(C(13)H(11)N(2)O)Cl(C(6)H(8)N(2))], the Cu(II) atom adopts a distorted tetra­hedral geometry being coordinated by the phenolic O atom and the azomethine N atom of the Schiff base ligand N-salicyl­idene 2-amino­pyridine, and by the 2-amino­pyridine N atom and a Cl atom. The pyridyl N atom of the Schiff base and the imino N atom of the 4-methyl-pyridine-2-yl­imino ligand are not involved in the coordination. There is an intra­molecular N—H⋯N hydrogen bond involving the pyridine N atom and the amino group of the 2-amino­pyridine ligand. In the crystal, mol­ecules are linked via N—H⋯Cl hydrogen bonds, forming chains propagating along [001].