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Chlorido(4-methylpyridin-2-amine-κN (1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II)
In the title complex, [Cu(C(13)H(11)N(2)O)Cl(C(6)H(8)N(2))], the Cu(II) atom adopts a distorted tetrahedral geometry being coordinated by the phenolic O atom and the azomethine N atom of the Schiff base ligand N-salicylidene 2-aminopyridine, and by the 2-aminopyridine N atom and a Cl atom. The p...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588768/ https://www.ncbi.nlm.nih.gov/pubmed/23468733 http://dx.doi.org/10.1107/S1600536812047198 |
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author | Bhagyaraju, Bussa Sambasiva Rao, P. Swu, Toka |
author_facet | Bhagyaraju, Bussa Sambasiva Rao, P. Swu, Toka |
author_sort | Bhagyaraju, Bussa |
collection | PubMed |
description | In the title complex, [Cu(C(13)H(11)N(2)O)Cl(C(6)H(8)N(2))], the Cu(II) atom adopts a distorted tetrahedral geometry being coordinated by the phenolic O atom and the azomethine N atom of the Schiff base ligand N-salicylidene 2-aminopyridine, and by the 2-aminopyridine N atom and a Cl atom. The pyridyl N atom of the Schiff base and the imino N atom of the 4-methyl-pyridine-2-ylimino ligand are not involved in the coordination. There is an intramolecular N—H⋯N hydrogen bond involving the pyridine N atom and the amino group of the 2-aminopyridine ligand. In the crystal, molecules are linked via N—H⋯Cl hydrogen bonds, forming chains propagating along [001]. |
format | Online Article Text |
id | pubmed-3588768 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887682013-03-06 Chlorido(4-methylpyridin-2-amine-κN (1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II) Bhagyaraju, Bussa Sambasiva Rao, P. Swu, Toka Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(13)H(11)N(2)O)Cl(C(6)H(8)N(2))], the Cu(II) atom adopts a distorted tetrahedral geometry being coordinated by the phenolic O atom and the azomethine N atom of the Schiff base ligand N-salicylidene 2-aminopyridine, and by the 2-aminopyridine N atom and a Cl atom. The pyridyl N atom of the Schiff base and the imino N atom of the 4-methyl-pyridine-2-ylimino ligand are not involved in the coordination. There is an intramolecular N—H⋯N hydrogen bond involving the pyridine N atom and the amino group of the 2-aminopyridine ligand. In the crystal, molecules are linked via N—H⋯Cl hydrogen bonds, forming chains propagating along [001]. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588768/ /pubmed/23468733 http://dx.doi.org/10.1107/S1600536812047198 Text en © Bhagyaraju et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bhagyaraju, Bussa Sambasiva Rao, P. Swu, Toka Chlorido(4-methylpyridin-2-amine-κN (1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II) |
title | Chlorido(4-methylpyridin-2-amine-κN
(1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II) |
title_full | Chlorido(4-methylpyridin-2-amine-κN
(1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II) |
title_fullStr | Chlorido(4-methylpyridin-2-amine-κN
(1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II) |
title_full_unstemmed | Chlorido(4-methylpyridin-2-amine-κN
(1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II) |
title_short | Chlorido(4-methylpyridin-2-amine-κN
(1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II) |
title_sort | chlorido(4-methylpyridin-2-amine-κn
(1))(2-{[(4-methylpyridin-2-yl)imino-κn]methyl}phenolato-κo)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588768/ https://www.ncbi.nlm.nih.gov/pubmed/23468733 http://dx.doi.org/10.1107/S1600536812047198 |
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