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Chlorido(4-methylpyridin-2-amine-κN (1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II)

In the title complex, [Cu(C(13)H(11)N(2)O)Cl(C(6)H(8)N(2))], the Cu(II) atom adopts a distorted tetra­hedral geometry being coordinated by the phenolic O atom and the azomethine N atom of the Schiff base ligand N-salicyl­idene 2-amino­pyridine, and by the 2-amino­pyridine N atom and a Cl atom. The p...

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Autores principales: Bhagyaraju, Bussa, Sambasiva Rao, P., Swu, Toka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588768/
https://www.ncbi.nlm.nih.gov/pubmed/23468733
http://dx.doi.org/10.1107/S1600536812047198
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author Bhagyaraju, Bussa
Sambasiva Rao, P.
Swu, Toka
author_facet Bhagyaraju, Bussa
Sambasiva Rao, P.
Swu, Toka
author_sort Bhagyaraju, Bussa
collection PubMed
description In the title complex, [Cu(C(13)H(11)N(2)O)Cl(C(6)H(8)N(2))], the Cu(II) atom adopts a distorted tetra­hedral geometry being coordinated by the phenolic O atom and the azomethine N atom of the Schiff base ligand N-salicyl­idene 2-amino­pyridine, and by the 2-amino­pyridine N atom and a Cl atom. The pyridyl N atom of the Schiff base and the imino N atom of the 4-methyl-pyridine-2-yl­imino ligand are not involved in the coordination. There is an intra­molecular N—H⋯N hydrogen bond involving the pyridine N atom and the amino group of the 2-amino­pyridine ligand. In the crystal, mol­ecules are linked via N—H⋯Cl hydrogen bonds, forming chains propagating along [001].
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spelling pubmed-35887682013-03-06 Chlorido(4-methylpyridin-2-amine-κN (1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II) Bhagyaraju, Bussa Sambasiva Rao, P. Swu, Toka Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(13)H(11)N(2)O)Cl(C(6)H(8)N(2))], the Cu(II) atom adopts a distorted tetra­hedral geometry being coordinated by the phenolic O atom and the azomethine N atom of the Schiff base ligand N-salicyl­idene 2-amino­pyridine, and by the 2-amino­pyridine N atom and a Cl atom. The pyridyl N atom of the Schiff base and the imino N atom of the 4-methyl-pyridine-2-yl­imino ligand are not involved in the coordination. There is an intra­molecular N—H⋯N hydrogen bond involving the pyridine N atom and the amino group of the 2-amino­pyridine ligand. In the crystal, mol­ecules are linked via N—H⋯Cl hydrogen bonds, forming chains propagating along [001]. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588768/ /pubmed/23468733 http://dx.doi.org/10.1107/S1600536812047198 Text en © Bhagyaraju et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bhagyaraju, Bussa
Sambasiva Rao, P.
Swu, Toka
Chlorido(4-methylpyridin-2-amine-κN (1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II)
title Chlorido(4-methylpyridin-2-amine-κN (1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II)
title_full Chlorido(4-methylpyridin-2-amine-κN (1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II)
title_fullStr Chlorido(4-methylpyridin-2-amine-κN (1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II)
title_full_unstemmed Chlorido(4-methylpyridin-2-amine-κN (1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II)
title_short Chlorido(4-methylpyridin-2-amine-κN (1))(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II)
title_sort chlorido(4-methylpyridin-2-amine-κn (1))(2-{[(4-methylpyridin-2-yl)imino-κn]methyl}phenolato-κo)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588768/
https://www.ncbi.nlm.nih.gov/pubmed/23468733
http://dx.doi.org/10.1107/S1600536812047198
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