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Tris(5,6-dimethyl-1,10-phenanthroline-κ(2) N,N′)iron(II) bis(tricyanomethanide)
The title compound, [Fe(C(14)H(12)N(2))(3)](C(4)N(3))(2), consists of one [Fe(dimephen)(3)](2+) complex cation (dimephen = 5,6-dimethyl-1,10-phenanthroline) and two uncoordinating tcm anions (tcm = tricyanomethanide). In the complex cation, the Fe(II) atom is coordinated by six N atoms from three c...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588769/ https://www.ncbi.nlm.nih.gov/pubmed/23468734 http://dx.doi.org/10.1107/S1600536812046880 |
Sumario: | The title compound, [Fe(C(14)H(12)N(2))(3)](C(4)N(3))(2), consists of one [Fe(dimephen)(3)](2+) complex cation (dimephen = 5,6-dimethyl-1,10-phenanthroline) and two uncoordinating tcm anions (tcm = tricyanomethanide). In the complex cation, the Fe(II) atom is coordinated by six N atoms from three chelating dimephen ligands at an average Fe—N distance of 1.963 (4) Å giving a distorted octahedral geometry. The crystal structure is stabilized by weak C—H⋯N hydrogen bonds and C N⋯π interactions between planar [maximum deviations of 0.024 (3) and 0.015 (3) Å] tcm anions and pyridine rings of dimephen [N2⋯centroid = 3.531 (3) and 3.726 (3) Å; C N⋯centroid = 96.4 (2) and 97.1 (2)°]. |
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