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Tris(5,6-dimethyl-1,10-phenanthroline-κ(2) N,N′)iron(II) bis­(tricyano­methanide)

The title compound, [Fe(C(14)H(12)N(2))(3)](C(4)N(3))(2), consists of one [Fe(dimephen)(3)](2+) complex cation (dimephen = 5,6-dimethyl-1,10-phenanthroline) and two uncoordinating tcm anions (tcm = tricyano­methanide). In the complex cation, the Fe(II) atom is coordinated by six N atoms from three c...

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Autores principales: Váhovská, Lucia, Potočňák, Ivan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588769/
https://www.ncbi.nlm.nih.gov/pubmed/23468734
http://dx.doi.org/10.1107/S1600536812046880
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author Váhovská, Lucia
Potočňák, Ivan
author_facet Váhovská, Lucia
Potočňák, Ivan
author_sort Váhovská, Lucia
collection PubMed
description The title compound, [Fe(C(14)H(12)N(2))(3)](C(4)N(3))(2), consists of one [Fe(dimephen)(3)](2+) complex cation (dimephen = 5,6-dimethyl-1,10-phenanthroline) and two uncoordinating tcm anions (tcm = tricyano­methanide). In the complex cation, the Fe(II) atom is coordinated by six N atoms from three chelating dimephen ligands at an average Fe—N distance of 1.963 (4) Å giving a distorted octa­hedral geometry. The crystal structure is stabilized by weak C—H⋯N hydrogen bonds and C N⋯π inter­actions between planar [maximum deviations of 0.024 (3) and 0.015 (3) Å] tcm anions and pyridine rings of dimephen [N2⋯centroid = 3.531 (3) and 3.726 (3) Å; C N⋯centroid = 96.4 (2) and 97.1 (2)°].
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spelling pubmed-35887692013-03-06 Tris(5,6-dimethyl-1,10-phenanthroline-κ(2) N,N′)iron(II) bis­(tricyano­methanide) Váhovská, Lucia Potočňák, Ivan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(14)H(12)N(2))(3)](C(4)N(3))(2), consists of one [Fe(dimephen)(3)](2+) complex cation (dimephen = 5,6-dimethyl-1,10-phenanthroline) and two uncoordinating tcm anions (tcm = tricyano­methanide). In the complex cation, the Fe(II) atom is coordinated by six N atoms from three chelating dimephen ligands at an average Fe—N distance of 1.963 (4) Å giving a distorted octa­hedral geometry. The crystal structure is stabilized by weak C—H⋯N hydrogen bonds and C N⋯π inter­actions between planar [maximum deviations of 0.024 (3) and 0.015 (3) Å] tcm anions and pyridine rings of dimephen [N2⋯centroid = 3.531 (3) and 3.726 (3) Å; C N⋯centroid = 96.4 (2) and 97.1 (2)°]. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588769/ /pubmed/23468734 http://dx.doi.org/10.1107/S1600536812046880 Text en © Váhovská and Potočňák 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Váhovská, Lucia
Potočňák, Ivan
Tris(5,6-dimethyl-1,10-phenanthroline-κ(2) N,N′)iron(II) bis­(tricyano­methanide)
title Tris(5,6-dimethyl-1,10-phenanthroline-κ(2) N,N′)iron(II) bis­(tricyano­methanide)
title_full Tris(5,6-dimethyl-1,10-phenanthroline-κ(2) N,N′)iron(II) bis­(tricyano­methanide)
title_fullStr Tris(5,6-dimethyl-1,10-phenanthroline-κ(2) N,N′)iron(II) bis­(tricyano­methanide)
title_full_unstemmed Tris(5,6-dimethyl-1,10-phenanthroline-κ(2) N,N′)iron(II) bis­(tricyano­methanide)
title_short Tris(5,6-dimethyl-1,10-phenanthroline-κ(2) N,N′)iron(II) bis­(tricyano­methanide)
title_sort tris(5,6-dimethyl-1,10-phenanthroline-κ(2) n,n′)iron(ii) bis­(tricyano­methanide)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588769/
https://www.ncbi.nlm.nih.gov/pubmed/23468734
http://dx.doi.org/10.1107/S1600536812046880
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