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Tris(5,6-dimethyl-1,10-phenanthroline-κ(2) N,N′)iron(II) bis(tricyanomethanide)
The title compound, [Fe(C(14)H(12)N(2))(3)](C(4)N(3))(2), consists of one [Fe(dimephen)(3)](2+) complex cation (dimephen = 5,6-dimethyl-1,10-phenanthroline) and two uncoordinating tcm anions (tcm = tricyanomethanide). In the complex cation, the Fe(II) atom is coordinated by six N atoms from three c...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588769/ https://www.ncbi.nlm.nih.gov/pubmed/23468734 http://dx.doi.org/10.1107/S1600536812046880 |
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author | Váhovská, Lucia Potočňák, Ivan |
author_facet | Váhovská, Lucia Potočňák, Ivan |
author_sort | Váhovská, Lucia |
collection | PubMed |
description | The title compound, [Fe(C(14)H(12)N(2))(3)](C(4)N(3))(2), consists of one [Fe(dimephen)(3)](2+) complex cation (dimephen = 5,6-dimethyl-1,10-phenanthroline) and two uncoordinating tcm anions (tcm = tricyanomethanide). In the complex cation, the Fe(II) atom is coordinated by six N atoms from three chelating dimephen ligands at an average Fe—N distance of 1.963 (4) Å giving a distorted octahedral geometry. The crystal structure is stabilized by weak C—H⋯N hydrogen bonds and C N⋯π interactions between planar [maximum deviations of 0.024 (3) and 0.015 (3) Å] tcm anions and pyridine rings of dimephen [N2⋯centroid = 3.531 (3) and 3.726 (3) Å; C N⋯centroid = 96.4 (2) and 97.1 (2)°]. |
format | Online Article Text |
id | pubmed-3588769 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887692013-03-06 Tris(5,6-dimethyl-1,10-phenanthroline-κ(2) N,N′)iron(II) bis(tricyanomethanide) Váhovská, Lucia Potočňák, Ivan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(14)H(12)N(2))(3)](C(4)N(3))(2), consists of one [Fe(dimephen)(3)](2+) complex cation (dimephen = 5,6-dimethyl-1,10-phenanthroline) and two uncoordinating tcm anions (tcm = tricyanomethanide). In the complex cation, the Fe(II) atom is coordinated by six N atoms from three chelating dimephen ligands at an average Fe—N distance of 1.963 (4) Å giving a distorted octahedral geometry. The crystal structure is stabilized by weak C—H⋯N hydrogen bonds and C N⋯π interactions between planar [maximum deviations of 0.024 (3) and 0.015 (3) Å] tcm anions and pyridine rings of dimephen [N2⋯centroid = 3.531 (3) and 3.726 (3) Å; C N⋯centroid = 96.4 (2) and 97.1 (2)°]. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588769/ /pubmed/23468734 http://dx.doi.org/10.1107/S1600536812046880 Text en © Váhovská and Potočňák 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Váhovská, Lucia Potočňák, Ivan Tris(5,6-dimethyl-1,10-phenanthroline-κ(2) N,N′)iron(II) bis(tricyanomethanide) |
title | Tris(5,6-dimethyl-1,10-phenanthroline-κ(2)
N,N′)iron(II) bis(tricyanomethanide) |
title_full | Tris(5,6-dimethyl-1,10-phenanthroline-κ(2)
N,N′)iron(II) bis(tricyanomethanide) |
title_fullStr | Tris(5,6-dimethyl-1,10-phenanthroline-κ(2)
N,N′)iron(II) bis(tricyanomethanide) |
title_full_unstemmed | Tris(5,6-dimethyl-1,10-phenanthroline-κ(2)
N,N′)iron(II) bis(tricyanomethanide) |
title_short | Tris(5,6-dimethyl-1,10-phenanthroline-κ(2)
N,N′)iron(II) bis(tricyanomethanide) |
title_sort | tris(5,6-dimethyl-1,10-phenanthroline-κ(2)
n,n′)iron(ii) bis(tricyanomethanide) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588769/ https://www.ncbi.nlm.nih.gov/pubmed/23468734 http://dx.doi.org/10.1107/S1600536812046880 |
work_keys_str_mv | AT vahovskalucia tris56dimethyl110phenanthrolinek2nnironiibistricyanomethanide AT potocnakivan tris56dimethyl110phenanthrolinek2nnironiibistricyanomethanide |