Di-μ-iodido-bis­[(biphenyl-2-yl)(triphenyl­phosphane-κP)palladium(II)]

In the title compound, [Pd(2)(C(12)H(9))(2)I(2)(C(18)H(15)P)(2)], the dimeric complex mol­ecule lies about an inversion center. The Pd⋯I⋯Pd bridges are slightly asymmetric, with Pd—I distances of 2.6709 (6) and 2.7486 (7) Å. The metal atom has a slightly puckered square-planar CI(2)P environment, th...

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Detalles Bibliográficos
Autores principales: Brown, Shayne, Crundwell, Guy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588770/
https://www.ncbi.nlm.nih.gov/pubmed/23468735
http://dx.doi.org/10.1107/S1600536812047733
Descripción
Sumario:In the title compound, [Pd(2)(C(12)H(9))(2)I(2)(C(18)H(15)P)(2)], the dimeric complex mol­ecule lies about an inversion center. The Pd⋯I⋯Pd bridges are slightly asymmetric, with Pd—I distances of 2.6709 (6) and 2.7486 (7) Å. The metal atom has a slightly puckered square-planar CI(2)P environment, the largest deviation from the least-squares plane being 0.143 (8) Å.

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