Di-μ-iodido-bis­[(biphenyl-2-yl)(triphenyl­phosphane-κP)palladium(II)]

In the title compound, [Pd(2)(C(12)H(9))(2)I(2)(C(18)H(15)P)(2)], the dimeric complex mol­ecule lies about an inversion center. The Pd⋯I⋯Pd bridges are slightly asymmetric, with Pd—I distances of 2.6709 (6) and 2.7486 (7) Å. The metal atom has a slightly puckered square-planar CI(2)P environment, th...

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Detalles Bibliográficos
Autores principales: Brown, Shayne, Crundwell, Guy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588770/
https://www.ncbi.nlm.nih.gov/pubmed/23468735
http://dx.doi.org/10.1107/S1600536812047733
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author Brown, Shayne
Crundwell, Guy
author_facet Brown, Shayne
Crundwell, Guy
author_sort Brown, Shayne
collection PubMed
description In the title compound, [Pd(2)(C(12)H(9))(2)I(2)(C(18)H(15)P)(2)], the dimeric complex mol­ecule lies about an inversion center. The Pd⋯I⋯Pd bridges are slightly asymmetric, with Pd—I distances of 2.6709 (6) and 2.7486 (7) Å. The metal atom has a slightly puckered square-planar CI(2)P environment, the largest deviation from the least-squares plane being 0.143 (8) Å.
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spelling pubmed-35887702013-03-06 Di-μ-iodido-bis­[(biphenyl-2-yl)(triphenyl­phosphane-κP)palladium(II)] Brown, Shayne Crundwell, Guy Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(2)(C(12)H(9))(2)I(2)(C(18)H(15)P)(2)], the dimeric complex mol­ecule lies about an inversion center. The Pd⋯I⋯Pd bridges are slightly asymmetric, with Pd—I distances of 2.6709 (6) and 2.7486 (7) Å. The metal atom has a slightly puckered square-planar CI(2)P environment, the largest deviation from the least-squares plane being 0.143 (8) Å. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588770/ /pubmed/23468735 http://dx.doi.org/10.1107/S1600536812047733 Text en © Brown and Crundwell 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Brown, Shayne
Crundwell, Guy
Di-μ-iodido-bis­[(biphenyl-2-yl)(triphenyl­phosphane-κP)palladium(II)]
title Di-μ-iodido-bis­[(biphenyl-2-yl)(triphenyl­phosphane-κP)palladium(II)]
title_full Di-μ-iodido-bis­[(biphenyl-2-yl)(triphenyl­phosphane-κP)palladium(II)]
title_fullStr Di-μ-iodido-bis­[(biphenyl-2-yl)(triphenyl­phosphane-κP)palladium(II)]
title_full_unstemmed Di-μ-iodido-bis­[(biphenyl-2-yl)(triphenyl­phosphane-κP)palladium(II)]
title_short Di-μ-iodido-bis­[(biphenyl-2-yl)(triphenyl­phosphane-κP)palladium(II)]
title_sort di-μ-iodido-bis­[(biphenyl-2-yl)(triphenyl­phosphane-κp)palladium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588770/
https://www.ncbi.nlm.nih.gov/pubmed/23468735
http://dx.doi.org/10.1107/S1600536812047733
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