[5-(Pyridin-2-yl)-1H-tetra­zole-κ(2) N (4),N (5)]bis(triphenyl­phosphane-κP)copper(I) tetra­fluoridoborate

In the title Cu(I) compound, [Cu(C(6)H(5)N(5))(C(18)H(15)P)(2)]BF(4), the Cu(I) cation is N,N′-chelated by a 5-(pyridin-2-yl)-1H-tetra­zole ligand and coordinated by two triphenyl­phosphane ligands in a distorted tetra­hedral geometry. The tetra­zole and pyridine rings are essentially coplanar [dihe...

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Detalles Bibliográficos
Autores principales: Lu, Lei, Yang, Ping, Li, Bing, Shi, Lin-Fang, Cao, Hua-Ru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588771/
https://www.ncbi.nlm.nih.gov/pubmed/23468736
http://dx.doi.org/10.1107/S1600536812047605
Descripción
Sumario:In the title Cu(I) compound, [Cu(C(6)H(5)N(5))(C(18)H(15)P)(2)]BF(4), the Cu(I) cation is N,N′-chelated by a 5-(pyridin-2-yl)-1H-tetra­zole ligand and coordinated by two triphenyl­phosphane ligands in a distorted tetra­hedral geometry. The tetra­zole and pyridine rings are essentially coplanar [dihedral angle = 4.1 (3)°]. The tetra­fluoridoborate anion links to the complex cation via an N—H⋯F hydrogen bond.

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