[5-(Pyridin-2-yl)-1H-tetra­zole-κ(2) N (4),N (5)]bis(triphenyl­phosphane-κP)copper(I) tetra­fluoridoborate

In the title Cu(I) compound, [Cu(C(6)H(5)N(5))(C(18)H(15)P)(2)]BF(4), the Cu(I) cation is N,N′-chelated by a 5-(pyridin-2-yl)-1H-tetra­zole ligand and coordinated by two triphenyl­phosphane ligands in a distorted tetra­hedral geometry. The tetra­zole and pyridine rings are essentially coplanar [dihe...

Descripción completa

Detalles Bibliográficos
Autores principales: Lu, Lei, Yang, Ping, Li, Bing, Shi, Lin-Fang, Cao, Hua-Ru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588771/
https://www.ncbi.nlm.nih.gov/pubmed/23468736
http://dx.doi.org/10.1107/S1600536812047605
_version_ 1782261633184169984
author Lu, Lei
Yang, Ping
Li, Bing
Shi, Lin-Fang
Cao, Hua-Ru
author_facet Lu, Lei
Yang, Ping
Li, Bing
Shi, Lin-Fang
Cao, Hua-Ru
author_sort Lu, Lei
collection PubMed
description In the title Cu(I) compound, [Cu(C(6)H(5)N(5))(C(18)H(15)P)(2)]BF(4), the Cu(I) cation is N,N′-chelated by a 5-(pyridin-2-yl)-1H-tetra­zole ligand and coordinated by two triphenyl­phosphane ligands in a distorted tetra­hedral geometry. The tetra­zole and pyridine rings are essentially coplanar [dihedral angle = 4.1 (3)°]. The tetra­fluoridoborate anion links to the complex cation via an N—H⋯F hydrogen bond.
format Online
Article
Text
id pubmed-3588771
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35887712013-03-06 [5-(Pyridin-2-yl)-1H-tetra­zole-κ(2) N (4),N (5)]bis(triphenyl­phosphane-κP)copper(I) tetra­fluoridoborate Lu, Lei Yang, Ping Li, Bing Shi, Lin-Fang Cao, Hua-Ru Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Cu(I) compound, [Cu(C(6)H(5)N(5))(C(18)H(15)P)(2)]BF(4), the Cu(I) cation is N,N′-chelated by a 5-(pyridin-2-yl)-1H-tetra­zole ligand and coordinated by two triphenyl­phosphane ligands in a distorted tetra­hedral geometry. The tetra­zole and pyridine rings are essentially coplanar [dihedral angle = 4.1 (3)°]. The tetra­fluoridoborate anion links to the complex cation via an N—H⋯F hydrogen bond. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588771/ /pubmed/23468736 http://dx.doi.org/10.1107/S1600536812047605 Text en © Lu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lu, Lei
Yang, Ping
Li, Bing
Shi, Lin-Fang
Cao, Hua-Ru
[5-(Pyridin-2-yl)-1H-tetra­zole-κ(2) N (4),N (5)]bis(triphenyl­phosphane-κP)copper(I) tetra­fluoridoborate
title [5-(Pyridin-2-yl)-1H-tetra­zole-κ(2) N (4),N (5)]bis(triphenyl­phosphane-κP)copper(I) tetra­fluoridoborate
title_full [5-(Pyridin-2-yl)-1H-tetra­zole-κ(2) N (4),N (5)]bis(triphenyl­phosphane-κP)copper(I) tetra­fluoridoborate
title_fullStr [5-(Pyridin-2-yl)-1H-tetra­zole-κ(2) N (4),N (5)]bis(triphenyl­phosphane-κP)copper(I) tetra­fluoridoborate
title_full_unstemmed [5-(Pyridin-2-yl)-1H-tetra­zole-κ(2) N (4),N (5)]bis(triphenyl­phosphane-κP)copper(I) tetra­fluoridoborate
title_short [5-(Pyridin-2-yl)-1H-tetra­zole-κ(2) N (4),N (5)]bis(triphenyl­phosphane-κP)copper(I) tetra­fluoridoborate
title_sort [5-(pyridin-2-yl)-1h-tetra­zole-κ(2) n (4),n (5)]bis(triphenyl­phosphane-κp)copper(i) tetra­fluoridoborate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588771/
https://www.ncbi.nlm.nih.gov/pubmed/23468736
http://dx.doi.org/10.1107/S1600536812047605
work_keys_str_mv AT lulei 5pyridin2yl1htetrazolek2n4n5bistriphenylphosphanekpcopperitetrafluoridoborate
AT yangping 5pyridin2yl1htetrazolek2n4n5bistriphenylphosphanekpcopperitetrafluoridoborate
AT libing 5pyridin2yl1htetrazolek2n4n5bistriphenylphosphanekpcopperitetrafluoridoborate
AT shilinfang 5pyridin2yl1htetrazolek2n4n5bistriphenylphosphanekpcopperitetrafluoridoborate
AT caohuaru 5pyridin2yl1htetrazolek2n4n5bistriphenylphosphanekpcopperitetrafluoridoborate

Ejemplares similares