Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III)–(nitrato-κ(2) O,O′)bis­(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III) (1/1)

The title co-crystal, [Eu(NCS)(3)(C(18)H(15)OP)(3)][Eu(NCS)(2)(NO(3))(C(18)H(15)OP)(3)], contains two distinct neutral complexes. Each complex has threefold symmetry about its central Eu(3+) ion. As a result, the nitrate-containing mol­ecule contains disorder of its bidentate nitrate and two N-bound...

Descripción completa

Detalles Bibliográficos
Autores principales: Thames, Anthony T., White, Frankie D., Pham, Lam N., Xiang, Kang Rui, Sykora, Richard E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588774/
https://www.ncbi.nlm.nih.gov/pubmed/23468739
http://dx.doi.org/10.1107/S1600536812047472
_version_ 1782261633859452928
author Thames, Anthony T.
White, Frankie D.
Pham, Lam N.
Xiang, Kang Rui
Sykora, Richard E.
author_facet Thames, Anthony T.
White, Frankie D.
Pham, Lam N.
Xiang, Kang Rui
Sykora, Richard E.
author_sort Thames, Anthony T.
collection PubMed
description The title co-crystal, [Eu(NCS)(3)(C(18)H(15)OP)(3)][Eu(NCS)(2)(NO(3))(C(18)H(15)OP)(3)], contains two distinct neutral complexes. Each complex has threefold symmetry about its central Eu(3+) ion. As a result, the nitrate-containing mol­ecule contains disorder of its bidentate nitrate and two N-bound thio­cyanate anions, while the [Eu(NCS)(3)(OPPh(3))(3)] complex is fully ordered. There is a weak π–π stacking inter­action between the phenyl rings of the two mol­ecules [centroid–centroid distance = 4.138 (4) Å].
format Online
Article
Text
id pubmed-3588774
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35887742013-03-06 Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III)–(nitrato-κ(2) O,O′)bis­(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III) (1/1) Thames, Anthony T. White, Frankie D. Pham, Lam N. Xiang, Kang Rui Sykora, Richard E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title co-crystal, [Eu(NCS)(3)(C(18)H(15)OP)(3)][Eu(NCS)(2)(NO(3))(C(18)H(15)OP)(3)], contains two distinct neutral complexes. Each complex has threefold symmetry about its central Eu(3+) ion. As a result, the nitrate-containing mol­ecule contains disorder of its bidentate nitrate and two N-bound thio­cyanate anions, while the [Eu(NCS)(3)(OPPh(3))(3)] complex is fully ordered. There is a weak π–π stacking inter­action between the phenyl rings of the two mol­ecules [centroid–centroid distance = 4.138 (4) Å]. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588774/ /pubmed/23468739 http://dx.doi.org/10.1107/S1600536812047472 Text en © Thames et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Thames, Anthony T.
White, Frankie D.
Pham, Lam N.
Xiang, Kang Rui
Sykora, Richard E.
Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III)–(nitrato-κ(2) O,O′)bis­(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III) (1/1)
title Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III)–(nitrato-κ(2) O,O′)bis­(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III) (1/1)
title_full Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III)–(nitrato-κ(2) O,O′)bis­(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III) (1/1)
title_fullStr Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III)–(nitrato-κ(2) O,O′)bis­(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III) (1/1)
title_full_unstemmed Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III)–(nitrato-κ(2) O,O′)bis­(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III) (1/1)
title_short Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III)–(nitrato-κ(2) O,O′)bis­(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)europium(III) (1/1)
title_sort tris(thio­cyanato-κn)tris­(triphenyl­phosphine oxide-κo)europium(iii)–(nitrato-κ(2) o,o′)bis­(thio­cyanato-κn)tris­(triphenyl­phosphine oxide-κo)europium(iii) (1/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588774/
https://www.ncbi.nlm.nih.gov/pubmed/23468739
http://dx.doi.org/10.1107/S1600536812047472
work_keys_str_mv AT thamesanthonyt tristhiocyanatokntristriphenylphosphineoxidekoeuropiumiiinitratok2oobisthiocyanatokntristriphenylphosphineoxidekoeuropiumiii11
AT whitefrankied tristhiocyanatokntristriphenylphosphineoxidekoeuropiumiiinitratok2oobisthiocyanatokntristriphenylphosphineoxidekoeuropiumiii11
AT phamlamn tristhiocyanatokntristriphenylphosphineoxidekoeuropiumiiinitratok2oobisthiocyanatokntristriphenylphosphineoxidekoeuropiumiii11
AT xiangkangrui tristhiocyanatokntristriphenylphosphineoxidekoeuropiumiiinitratok2oobisthiocyanatokntristriphenylphosphineoxidekoeuropiumiii11
AT sykoraricharde tristhiocyanatokntristriphenylphosphineoxidekoeuropiumiiinitratok2oobisthiocyanatokntristriphenylphosphineoxidekoeuropiumiii11

Ejemplares similares