Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)terbium(III)

The title compound, [Tb(NCS)(3)(C(18)H(15)OP)(3)], contains a six-coordinate Tb(II) cation surrounded by three O-bound triphenyl­phosphine oxide ligands and three N-bound thio­cyanate ligands, each in a fac arrangement. There are two crystallographically unique Tb(III) atoms in the asymmetric unit....

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Autores principales: Pham, Lam N., Thames, Anthony T., White, Frankie D., Xiang, Kang Rui, Sykora, Richard E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588775/
https://www.ncbi.nlm.nih.gov/pubmed/23468740
http://dx.doi.org/10.1107/S1600536812047289
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author Pham, Lam N.
Thames, Anthony T.
White, Frankie D.
Xiang, Kang Rui
Sykora, Richard E.
author_facet Pham, Lam N.
Thames, Anthony T.
White, Frankie D.
Xiang, Kang Rui
Sykora, Richard E.
author_sort Pham, Lam N.
collection PubMed
description The title compound, [Tb(NCS)(3)(C(18)H(15)OP)(3)], contains a six-coordinate Tb(II) cation surrounded by three O-bound triphenyl­phosphine oxide ligands and three N-bound thio­cyanate ligands, each in a fac arrangement. There are two crystallographically unique Tb(III) atoms in the asymmetric unit. One Tb(III) atom resides on a threefold rotation axis, while the other has no imposed crystallographic symmetry. The thio­cyanate ligands are bound through N atoms, illustrating the hard–hard bonding principles of metal complex chemistry.
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spelling pubmed-35887752013-03-06 Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)terbium(III) Pham, Lam N. Thames, Anthony T. White, Frankie D. Xiang, Kang Rui Sykora, Richard E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Tb(NCS)(3)(C(18)H(15)OP)(3)], contains a six-coordinate Tb(II) cation surrounded by three O-bound triphenyl­phosphine oxide ligands and three N-bound thio­cyanate ligands, each in a fac arrangement. There are two crystallographically unique Tb(III) atoms in the asymmetric unit. One Tb(III) atom resides on a threefold rotation axis, while the other has no imposed crystallographic symmetry. The thio­cyanate ligands are bound through N atoms, illustrating the hard–hard bonding principles of metal complex chemistry. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588775/ /pubmed/23468740 http://dx.doi.org/10.1107/S1600536812047289 Text en © Pham et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pham, Lam N.
Thames, Anthony T.
White, Frankie D.
Xiang, Kang Rui
Sykora, Richard E.
Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)terbium(III)
title Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)terbium(III)
title_full Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)terbium(III)
title_fullStr Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)terbium(III)
title_full_unstemmed Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)terbium(III)
title_short Tris(thio­cyanato-κN)tris­(triphenyl­phosphine oxide-κO)terbium(III)
title_sort tris(thio­cyanato-κn)tris­(triphenyl­phosphine oxide-κo)terbium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588775/
https://www.ncbi.nlm.nih.gov/pubmed/23468740
http://dx.doi.org/10.1107/S1600536812047289
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