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(4-{[(Pyridin-4-yl)methyl­idene]amino}­phen­yl)ferrocene

The asymetric unit of the title compound, [Fe(C(5)H(5))(C(17)H(13)N(2))], contains two independent mol­ecules whose conformations differ, especially in the 4-{(pyridin-4-yl)methyl­idene]amino}­phenyl unit where one is flipped by almost 180°. The cyclo­penta­dienyl rings of the ferrocene unit also ex...

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Detalles Bibliográficos
Autores principales: Nyamori, Vincent O., Keru, Godfrey, Omondi, Bernard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588778/
https://www.ncbi.nlm.nih.gov/pubmed/23468743
http://dx.doi.org/10.1107/S1600536812047812
Descripción
Sumario:The asymetric unit of the title compound, [Fe(C(5)H(5))(C(17)H(13)N(2))], contains two independent mol­ecules whose conformations differ, especially in the 4-{(pyridin-4-yl)methyl­idene]amino}­phenyl unit where one is flipped by almost 180°. The cyclo­penta­dienyl rings of the ferrocene unit also exhibit different staggered conformations: in one mol­ecule the conformation is staggered by 9.43 (2)° and in the other by 24.46 (1)° from an ideal eclipsed geometry. The plane of the benzene ring is tilted away from the ferrocene group in both mol­ecules, with dihedral angles of 6.97 (1) and 10.30 (2)°. The benzene ring is also slightly twisted from the plane of the pyridine ring, with dihedral angles of 5.98 (2) and 6.51 (2)° in the two mol­ecules.