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(4-{[(Pyridin-4-yl)methylidene]amino}phenyl)ferrocene
The asymetric unit of the title compound, [Fe(C(5)H(5))(C(17)H(13)N(2))], contains two independent molecules whose conformations differ, especially in the 4-{(pyridin-4-yl)methylidene]amino}phenyl unit where one is flipped by almost 180°. The cyclopentadienyl rings of the ferrocene unit also ex...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588778/ https://www.ncbi.nlm.nih.gov/pubmed/23468743 http://dx.doi.org/10.1107/S1600536812047812 |
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author | Nyamori, Vincent O. Keru, Godfrey Omondi, Bernard |
author_facet | Nyamori, Vincent O. Keru, Godfrey Omondi, Bernard |
author_sort | Nyamori, Vincent O. |
collection | PubMed |
description | The asymetric unit of the title compound, [Fe(C(5)H(5))(C(17)H(13)N(2))], contains two independent molecules whose conformations differ, especially in the 4-{(pyridin-4-yl)methylidene]amino}phenyl unit where one is flipped by almost 180°. The cyclopentadienyl rings of the ferrocene unit also exhibit different staggered conformations: in one molecule the conformation is staggered by 9.43 (2)° and in the other by 24.46 (1)° from an ideal eclipsed geometry. The plane of the benzene ring is tilted away from the ferrocene group in both molecules, with dihedral angles of 6.97 (1) and 10.30 (2)°. The benzene ring is also slightly twisted from the plane of the pyridine ring, with dihedral angles of 5.98 (2) and 6.51 (2)° in the two molecules. |
format | Online Article Text |
id | pubmed-3588778 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887782013-03-06 (4-{[(Pyridin-4-yl)methylidene]amino}phenyl)ferrocene Nyamori, Vincent O. Keru, Godfrey Omondi, Bernard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymetric unit of the title compound, [Fe(C(5)H(5))(C(17)H(13)N(2))], contains two independent molecules whose conformations differ, especially in the 4-{(pyridin-4-yl)methylidene]amino}phenyl unit where one is flipped by almost 180°. The cyclopentadienyl rings of the ferrocene unit also exhibit different staggered conformations: in one molecule the conformation is staggered by 9.43 (2)° and in the other by 24.46 (1)° from an ideal eclipsed geometry. The plane of the benzene ring is tilted away from the ferrocene group in both molecules, with dihedral angles of 6.97 (1) and 10.30 (2)°. The benzene ring is also slightly twisted from the plane of the pyridine ring, with dihedral angles of 5.98 (2) and 6.51 (2)° in the two molecules. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588778/ /pubmed/23468743 http://dx.doi.org/10.1107/S1600536812047812 Text en © Nyamori et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Nyamori, Vincent O. Keru, Godfrey Omondi, Bernard (4-{[(Pyridin-4-yl)methylidene]amino}phenyl)ferrocene |
title | (4-{[(Pyridin-4-yl)methylidene]amino}phenyl)ferrocene |
title_full | (4-{[(Pyridin-4-yl)methylidene]amino}phenyl)ferrocene |
title_fullStr | (4-{[(Pyridin-4-yl)methylidene]amino}phenyl)ferrocene |
title_full_unstemmed | (4-{[(Pyridin-4-yl)methylidene]amino}phenyl)ferrocene |
title_short | (4-{[(Pyridin-4-yl)methylidene]amino}phenyl)ferrocene |
title_sort | (4-{[(pyridin-4-yl)methylidene]amino}phenyl)ferrocene |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588778/ https://www.ncbi.nlm.nih.gov/pubmed/23468743 http://dx.doi.org/10.1107/S1600536812047812 |
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