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(4-{[(Pyridin-4-yl)methyl­idene]amino}­phen­yl)ferrocene

The asymetric unit of the title compound, [Fe(C(5)H(5))(C(17)H(13)N(2))], contains two independent mol­ecules whose conformations differ, especially in the 4-{(pyridin-4-yl)methyl­idene]amino}­phenyl unit where one is flipped by almost 180°. The cyclo­penta­dienyl rings of the ferrocene unit also ex...

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Detalles Bibliográficos
Autores principales: Nyamori, Vincent O., Keru, Godfrey, Omondi, Bernard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588778/
https://www.ncbi.nlm.nih.gov/pubmed/23468743
http://dx.doi.org/10.1107/S1600536812047812
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author Nyamori, Vincent O.
Keru, Godfrey
Omondi, Bernard
author_facet Nyamori, Vincent O.
Keru, Godfrey
Omondi, Bernard
author_sort Nyamori, Vincent O.
collection PubMed
description The asymetric unit of the title compound, [Fe(C(5)H(5))(C(17)H(13)N(2))], contains two independent mol­ecules whose conformations differ, especially in the 4-{(pyridin-4-yl)methyl­idene]amino}­phenyl unit where one is flipped by almost 180°. The cyclo­penta­dienyl rings of the ferrocene unit also exhibit different staggered conformations: in one mol­ecule the conformation is staggered by 9.43 (2)° and in the other by 24.46 (1)° from an ideal eclipsed geometry. The plane of the benzene ring is tilted away from the ferrocene group in both mol­ecules, with dihedral angles of 6.97 (1) and 10.30 (2)°. The benzene ring is also slightly twisted from the plane of the pyridine ring, with dihedral angles of 5.98 (2) and 6.51 (2)° in the two mol­ecules.
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spelling pubmed-35887782013-03-06 (4-{[(Pyridin-4-yl)methyl­idene]amino}­phen­yl)ferrocene Nyamori, Vincent O. Keru, Godfrey Omondi, Bernard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymetric unit of the title compound, [Fe(C(5)H(5))(C(17)H(13)N(2))], contains two independent mol­ecules whose conformations differ, especially in the 4-{(pyridin-4-yl)methyl­idene]amino}­phenyl unit where one is flipped by almost 180°. The cyclo­penta­dienyl rings of the ferrocene unit also exhibit different staggered conformations: in one mol­ecule the conformation is staggered by 9.43 (2)° and in the other by 24.46 (1)° from an ideal eclipsed geometry. The plane of the benzene ring is tilted away from the ferrocene group in both mol­ecules, with dihedral angles of 6.97 (1) and 10.30 (2)°. The benzene ring is also slightly twisted from the plane of the pyridine ring, with dihedral angles of 5.98 (2) and 6.51 (2)° in the two mol­ecules. International Union of Crystallography 2012-11-24 /pmc/articles/PMC3588778/ /pubmed/23468743 http://dx.doi.org/10.1107/S1600536812047812 Text en © Nyamori et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nyamori, Vincent O.
Keru, Godfrey
Omondi, Bernard
(4-{[(Pyridin-4-yl)methyl­idene]amino}­phen­yl)ferrocene
title (4-{[(Pyridin-4-yl)methyl­idene]amino}­phen­yl)ferrocene
title_full (4-{[(Pyridin-4-yl)methyl­idene]amino}­phen­yl)ferrocene
title_fullStr (4-{[(Pyridin-4-yl)methyl­idene]amino}­phen­yl)ferrocene
title_full_unstemmed (4-{[(Pyridin-4-yl)methyl­idene]amino}­phen­yl)ferrocene
title_short (4-{[(Pyridin-4-yl)methyl­idene]amino}­phen­yl)ferrocene
title_sort (4-{[(pyridin-4-yl)methyl­idene]amino}­phen­yl)ferrocene
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588778/
https://www.ncbi.nlm.nih.gov/pubmed/23468743
http://dx.doi.org/10.1107/S1600536812047812
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