Tetra­kis(triphenyl­phosphane-κP)silver(I) trifluoro­acetate ethanol monosolvate

In the title solvated salt, [Ag(C(18)H(15)P)(4)](CF(3)CO(2))·C(2)H(5)OH, the Ag(I) atom is coordinated by four P atoms from triphenyl­phosphane ligands in a distorted tetra­hedral geometry. The anion and solvent are engaged in weak O—H⋯O hydrogen bonds. Of the four triphenyl­phosphane ligands, two e...

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Detalles Bibliográficos
Autor principal: Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588779/
https://www.ncbi.nlm.nih.gov/pubmed/23468744
http://dx.doi.org/10.1107/S1600536812045060
Descripción
Sumario:In the title solvated salt, [Ag(C(18)H(15)P)(4)](CF(3)CO(2))·C(2)H(5)OH, the Ag(I) atom is coordinated by four P atoms from triphenyl­phosphane ligands in a distorted tetra­hedral geometry. The anion and solvent are engaged in weak O—H⋯O hydrogen bonds. Of the four triphenyl­phosphane ligands, two each have an equally disordered phenyl ring while the Ag(I) atom is disordered over two positions in a 0.9595 (15):0.0405 (15) ratio and the trifluoro­acetate anion is equally disordered over two positions with respect to the lattice ethanol mol­ecule.

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