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Tetrakis(triphenylphosphane-κP)silver(I) trifluoroacetate ethanol monosolvate
In the title solvated salt, [Ag(C(18)H(15)P)(4)](CF(3)CO(2))·C(2)H(5)OH, the Ag(I) atom is coordinated by four P atoms from triphenylphosphane ligands in a distorted tetrahedral geometry. The anion and solvent are engaged in weak O—H⋯O hydrogen bonds. Of the four triphenylphosphane ligands, two e...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588779/ https://www.ncbi.nlm.nih.gov/pubmed/23468744 http://dx.doi.org/10.1107/S1600536812045060 |
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| author | Ng, Seik Weng |
| author_facet | Ng, Seik Weng |
| author_sort | Ng, Seik Weng |
| collection | PubMed |
| description | In the title solvated salt, [Ag(C(18)H(15)P)(4)](CF(3)CO(2))·C(2)H(5)OH, the Ag(I) atom is coordinated by four P atoms from triphenylphosphane ligands in a distorted tetrahedral geometry. The anion and solvent are engaged in weak O—H⋯O hydrogen bonds. Of the four triphenylphosphane ligands, two each have an equally disordered phenyl ring while the Ag(I) atom is disordered over two positions in a 0.9595 (15):0.0405 (15) ratio and the trifluoroacetate anion is equally disordered over two positions with respect to the lattice ethanol molecule. |
| format | Online Article Text |
| id | pubmed-3588779 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35887792013-03-06 Tetrakis(triphenylphosphane-κP)silver(I) trifluoroacetate ethanol monosolvate Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title solvated salt, [Ag(C(18)H(15)P)(4)](CF(3)CO(2))·C(2)H(5)OH, the Ag(I) atom is coordinated by four P atoms from triphenylphosphane ligands in a distorted tetrahedral geometry. The anion and solvent are engaged in weak O—H⋯O hydrogen bonds. Of the four triphenylphosphane ligands, two each have an equally disordered phenyl ring while the Ag(I) atom is disordered over two positions in a 0.9595 (15):0.0405 (15) ratio and the trifluoroacetate anion is equally disordered over two positions with respect to the lattice ethanol molecule. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588779/ /pubmed/23468744 http://dx.doi.org/10.1107/S1600536812045060 Text en © Seik Weng Ng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ng, Seik Weng Tetrakis(triphenylphosphane-κP)silver(I) trifluoroacetate ethanol monosolvate |
| title | Tetrakis(triphenylphosphane-κP)silver(I) trifluoroacetate ethanol monosolvate |
| title_full | Tetrakis(triphenylphosphane-κP)silver(I) trifluoroacetate ethanol monosolvate |
| title_fullStr | Tetrakis(triphenylphosphane-κP)silver(I) trifluoroacetate ethanol monosolvate |
| title_full_unstemmed | Tetrakis(triphenylphosphane-κP)silver(I) trifluoroacetate ethanol monosolvate |
| title_short | Tetrakis(triphenylphosphane-κP)silver(I) trifluoroacetate ethanol monosolvate |
| title_sort | tetrakis(triphenylphosphane-κp)silver(i) trifluoroacetate ethanol monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588779/ https://www.ncbi.nlm.nih.gov/pubmed/23468744 http://dx.doi.org/10.1107/S1600536812045060 |
| work_keys_str_mv | AT ngseikweng tetrakistriphenylphosphanekpsilveritrifluoroacetateethanolmonosolvate |