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Tetrakis(triphenylarsane-κAs)silver(I) trifluoroacetate hemihydrate methanol hemisolvate
The Ag(I) atom in the title hydrated solvated salt, [Ag(C(18)H(15)As)(4)](CF(3)CO(2))·0.5CH(3)OH·0.5H(2)O, is coordinated by four As atoms from triphenylarsane ligands in a distorted tetrahedral geometry. In the crystal, O—H⋯O hydrogen bonding occurs between carboxylate groups of anions and latti...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588780/ https://www.ncbi.nlm.nih.gov/pubmed/23468745 http://dx.doi.org/10.1107/S1600536812045072 |
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author | Ng, Seik Weng |
author_facet | Ng, Seik Weng |
author_sort | Ng, Seik Weng |
collection | PubMed |
description | The Ag(I) atom in the title hydrated solvated salt, [Ag(C(18)H(15)As)(4)](CF(3)CO(2))·0.5CH(3)OH·0.5H(2)O, is coordinated by four As atoms from triphenylarsane ligands in a distorted tetrahedral geometry. In the crystal, O—H⋯O hydrogen bonding occurs between carboxylate groups of anions and lattice solvent molecules. Of the four triphenylarsane ligands in the Ag complex cation, two each have an equally disordered phenyl ring while the trifluoroacetate anion is disordered over two positions with respect to the lattice methanol and water molecules which both show half-occupyncy. The crystal studied was a non-merohedral twin with a 13.6 (1)% contribution of the minor twin component. |
format | Online Article Text |
id | pubmed-3588780 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887802013-03-06 Tetrakis(triphenylarsane-κAs)silver(I) trifluoroacetate hemihydrate methanol hemisolvate Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ag(I) atom in the title hydrated solvated salt, [Ag(C(18)H(15)As)(4)](CF(3)CO(2))·0.5CH(3)OH·0.5H(2)O, is coordinated by four As atoms from triphenylarsane ligands in a distorted tetrahedral geometry. In the crystal, O—H⋯O hydrogen bonding occurs between carboxylate groups of anions and lattice solvent molecules. Of the four triphenylarsane ligands in the Ag complex cation, two each have an equally disordered phenyl ring while the trifluoroacetate anion is disordered over two positions with respect to the lattice methanol and water molecules which both show half-occupyncy. The crystal studied was a non-merohedral twin with a 13.6 (1)% contribution of the minor twin component. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588780/ /pubmed/23468745 http://dx.doi.org/10.1107/S1600536812045072 Text en © Seik Weng Ng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ng, Seik Weng Tetrakis(triphenylarsane-κAs)silver(I) trifluoroacetate hemihydrate methanol hemisolvate |
title | Tetrakis(triphenylarsane-κAs)silver(I) trifluoroacetate hemihydrate methanol hemisolvate |
title_full | Tetrakis(triphenylarsane-κAs)silver(I) trifluoroacetate hemihydrate methanol hemisolvate |
title_fullStr | Tetrakis(triphenylarsane-κAs)silver(I) trifluoroacetate hemihydrate methanol hemisolvate |
title_full_unstemmed | Tetrakis(triphenylarsane-κAs)silver(I) trifluoroacetate hemihydrate methanol hemisolvate |
title_short | Tetrakis(triphenylarsane-κAs)silver(I) trifluoroacetate hemihydrate methanol hemisolvate |
title_sort | tetrakis(triphenylarsane-κas)silver(i) trifluoroacetate hemihydrate methanol hemisolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588780/ https://www.ncbi.nlm.nih.gov/pubmed/23468745 http://dx.doi.org/10.1107/S1600536812045072 |
work_keys_str_mv | AT ngseikweng tetrakistriphenylarsanekassilveritrifluoroacetatehemihydratemethanolhemisolvate |