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Tetra­kis(triphenyl­arsane-κAs)silver(I) trifluoro­acetate hemihydrate methanol hemisolvate

The Ag(I) atom in the title hydrated solvated salt, [Ag(C(18)H(15)As)(4)](CF(3)CO(2))·0.5CH(3)OH·0.5H(2)O, is coordinated by four As atoms from triphenyl­arsane ligands in a distorted tetra­hedral geometry. In the crystal, O—H⋯O hydrogen bonding occurs between carboxyl­ate groups of anions and latti...

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Autor principal: Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588780/
https://www.ncbi.nlm.nih.gov/pubmed/23468745
http://dx.doi.org/10.1107/S1600536812045072
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author Ng, Seik Weng
author_facet Ng, Seik Weng
author_sort Ng, Seik Weng
collection PubMed
description The Ag(I) atom in the title hydrated solvated salt, [Ag(C(18)H(15)As)(4)](CF(3)CO(2))·0.5CH(3)OH·0.5H(2)O, is coordinated by four As atoms from triphenyl­arsane ligands in a distorted tetra­hedral geometry. In the crystal, O—H⋯O hydrogen bonding occurs between carboxyl­ate groups of anions and lattice solvent mol­ecules. Of the four triphenyl­arsane ligands in the Ag complex cation, two each have an equally disordered phenyl ring while the trifluoro­acetate anion is disordered over two positions with respect to the lattice methanol and water mol­ecules which both show half-occupyncy. The crystal studied was a non-merohedral twin with a 13.6 (1)% contribution of the minor twin component.
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spelling pubmed-35887802013-03-06 Tetra­kis(triphenyl­arsane-κAs)silver(I) trifluoro­acetate hemihydrate methanol hemisolvate Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ag(I) atom in the title hydrated solvated salt, [Ag(C(18)H(15)As)(4)](CF(3)CO(2))·0.5CH(3)OH·0.5H(2)O, is coordinated by four As atoms from triphenyl­arsane ligands in a distorted tetra­hedral geometry. In the crystal, O—H⋯O hydrogen bonding occurs between carboxyl­ate groups of anions and lattice solvent mol­ecules. Of the four triphenyl­arsane ligands in the Ag complex cation, two each have an equally disordered phenyl ring while the trifluoro­acetate anion is disordered over two positions with respect to the lattice methanol and water mol­ecules which both show half-occupyncy. The crystal studied was a non-merohedral twin with a 13.6 (1)% contribution of the minor twin component. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588780/ /pubmed/23468745 http://dx.doi.org/10.1107/S1600536812045072 Text en © Seik Weng Ng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ng, Seik Weng
Tetra­kis(triphenyl­arsane-κAs)silver(I) trifluoro­acetate hemihydrate methanol hemisolvate
title Tetra­kis(triphenyl­arsane-κAs)silver(I) trifluoro­acetate hemihydrate methanol hemisolvate
title_full Tetra­kis(triphenyl­arsane-κAs)silver(I) trifluoro­acetate hemihydrate methanol hemisolvate
title_fullStr Tetra­kis(triphenyl­arsane-κAs)silver(I) trifluoro­acetate hemihydrate methanol hemisolvate
title_full_unstemmed Tetra­kis(triphenyl­arsane-κAs)silver(I) trifluoro­acetate hemihydrate methanol hemisolvate
title_short Tetra­kis(triphenyl­arsane-κAs)silver(I) trifluoro­acetate hemihydrate methanol hemisolvate
title_sort tetra­kis(triphenyl­arsane-κas)silver(i) trifluoro­acetate hemihydrate methanol hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588780/
https://www.ncbi.nlm.nih.gov/pubmed/23468745
http://dx.doi.org/10.1107/S1600536812045072
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