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(Nitrato-κ(2) O,O′)bis­[(E)-N-(pyridin-4-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)

In the mononuclear title compound, [Ag(NO(3))(C(6)H(6)N(2)O)(2)], the Ag(I) atom is located on a twofold rotation axis and the nitrate-chelated Ag(I) atom is further coordinated by two aromatic N atoms of hydroxyl­amine ligands in a distorted tetra­hedral geometry. In the crystal, the nitrate ion ha...

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Autores principales: Gao, Shan, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588783/
https://www.ncbi.nlm.nih.gov/pubmed/23468748
http://dx.doi.org/10.1107/S1600536812046107
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author Gao, Shan
Ng, Seik Weng
author_facet Gao, Shan
Ng, Seik Weng
author_sort Gao, Shan
collection PubMed
description In the mononuclear title compound, [Ag(NO(3))(C(6)H(6)N(2)O)(2)], the Ag(I) atom is located on a twofold rotation axis and the nitrate-chelated Ag(I) atom is further coordinated by two aromatic N atoms of hydroxyl­amine ligands in a distorted tetra­hedral geometry. In the crystal, the nitrate ion has 2 symmetry with the N atom and one O atom located on the twofold rotation axis, and is linked to hy­droxy groups of the hydroxyl­amine ligands by O—H⋯O hydrogen bonds, generating a chain running along the b axis.
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spelling pubmed-35887832013-03-06 (Nitrato-κ(2) O,O′)bis­[(E)-N-(pyridin-4-yl­methyl­idene-κN)hy­droxy­amine]­silver(I) Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title compound, [Ag(NO(3))(C(6)H(6)N(2)O)(2)], the Ag(I) atom is located on a twofold rotation axis and the nitrate-chelated Ag(I) atom is further coordinated by two aromatic N atoms of hydroxyl­amine ligands in a distorted tetra­hedral geometry. In the crystal, the nitrate ion has 2 symmetry with the N atom and one O atom located on the twofold rotation axis, and is linked to hy­droxy groups of the hydroxyl­amine ligands by O—H⋯O hydrogen bonds, generating a chain running along the b axis. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588783/ /pubmed/23468748 http://dx.doi.org/10.1107/S1600536812046107 Text en © Gao and Ng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Shan
Ng, Seik Weng
(Nitrato-κ(2) O,O′)bis­[(E)-N-(pyridin-4-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)
title (Nitrato-κ(2) O,O′)bis­[(E)-N-(pyridin-4-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)
title_full (Nitrato-κ(2) O,O′)bis­[(E)-N-(pyridin-4-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)
title_fullStr (Nitrato-κ(2) O,O′)bis­[(E)-N-(pyridin-4-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)
title_full_unstemmed (Nitrato-κ(2) O,O′)bis­[(E)-N-(pyridin-4-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)
title_short (Nitrato-κ(2) O,O′)bis­[(E)-N-(pyridin-4-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)
title_sort (nitrato-κ(2) o,o′)bis­[(e)-n-(pyridin-4-yl­methyl­idene-κn)hy­droxy­amine]­silver(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588783/
https://www.ncbi.nlm.nih.gov/pubmed/23468748
http://dx.doi.org/10.1107/S1600536812046107
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