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(Nitrato-κ(2) O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I)
In the mononuclear title compound, [Ag(NO(3))(C(6)H(6)N(2)O)(2)], the Ag(I) atom is located on a twofold rotation axis and the nitrate-chelated Ag(I) atom is further coordinated by two aromatic N atoms of hydroxylamine ligands in a distorted tetrahedral geometry. In the crystal, the nitrate ion ha...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588783/ https://www.ncbi.nlm.nih.gov/pubmed/23468748 http://dx.doi.org/10.1107/S1600536812046107 |
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author | Gao, Shan Ng, Seik Weng |
author_facet | Gao, Shan Ng, Seik Weng |
author_sort | Gao, Shan |
collection | PubMed |
description | In the mononuclear title compound, [Ag(NO(3))(C(6)H(6)N(2)O)(2)], the Ag(I) atom is located on a twofold rotation axis and the nitrate-chelated Ag(I) atom is further coordinated by two aromatic N atoms of hydroxylamine ligands in a distorted tetrahedral geometry. In the crystal, the nitrate ion has 2 symmetry with the N atom and one O atom located on the twofold rotation axis, and is linked to hydroxy groups of the hydroxylamine ligands by O—H⋯O hydrogen bonds, generating a chain running along the b axis. |
format | Online Article Text |
id | pubmed-3588783 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887832013-03-06 (Nitrato-κ(2) O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I) Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title compound, [Ag(NO(3))(C(6)H(6)N(2)O)(2)], the Ag(I) atom is located on a twofold rotation axis and the nitrate-chelated Ag(I) atom is further coordinated by two aromatic N atoms of hydroxylamine ligands in a distorted tetrahedral geometry. In the crystal, the nitrate ion has 2 symmetry with the N atom and one O atom located on the twofold rotation axis, and is linked to hydroxy groups of the hydroxylamine ligands by O—H⋯O hydrogen bonds, generating a chain running along the b axis. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588783/ /pubmed/23468748 http://dx.doi.org/10.1107/S1600536812046107 Text en © Gao and Ng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Shan Ng, Seik Weng (Nitrato-κ(2) O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I) |
title | (Nitrato-κ(2)
O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I) |
title_full | (Nitrato-κ(2)
O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I) |
title_fullStr | (Nitrato-κ(2)
O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I) |
title_full_unstemmed | (Nitrato-κ(2)
O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I) |
title_short | (Nitrato-κ(2)
O,O′)bis[(E)-N-(pyridin-4-ylmethylidene-κN)hydroxyamine]silver(I) |
title_sort | (nitrato-κ(2)
o,o′)bis[(e)-n-(pyridin-4-ylmethylidene-κn)hydroxyamine]silver(i) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588783/ https://www.ncbi.nlm.nih.gov/pubmed/23468748 http://dx.doi.org/10.1107/S1600536812046107 |
work_keys_str_mv | AT gaoshan nitratok2oobisenpyridin4ylmethylideneknhydroxyaminesilveri AT ngseikweng nitratok2oobisenpyridin4ylmethylideneknhydroxyaminesilveri |