Tris{2-[(pyrimidin-2-yl-κN)amino­meth­yl]phenol}silver(I) nitrate

The Ag(I) atom in the title compound, [Ag(C(11)H(11)N(3)O)(3)]NO(3), shows a T-shaped coordination arising from bonding to the N atom of three N-heterocycles; the geometry is distorted towards square pyramidal owing to two weak Ag⋯O(nitrate) inter­actions [Ag⋯O = 2.691 (5) and 3.073 (5) Å]. The cati...

Descripción completa

Detalles Bibliográficos
Autores principales: Gao, Shan, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588784/
https://www.ncbi.nlm.nih.gov/pubmed/23468749
http://dx.doi.org/10.1107/S1600536812046119
_version_ 1782261636255449088
author Gao, Shan
Ng, Seik Weng
author_facet Gao, Shan
Ng, Seik Weng
author_sort Gao, Shan
collection PubMed
description The Ag(I) atom in the title compound, [Ag(C(11)H(11)N(3)O)(3)]NO(3), shows a T-shaped coordination arising from bonding to the N atom of three N-heterocycles; the geometry is distorted towards square pyramidal owing to two weak Ag⋯O(nitrate) inter­actions [Ag⋯O = 2.691 (5) and 3.073 (5) Å]. The cation and anion are linked by O—H⋯N and N—H⋯O hydrogen bonds, generating a three-dimensional network.
format Online
Article
Text
id pubmed-3588784
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35887842013-03-06 Tris{2-[(pyrimidin-2-yl-κN)amino­meth­yl]phenol}silver(I) nitrate Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ag(I) atom in the title compound, [Ag(C(11)H(11)N(3)O)(3)]NO(3), shows a T-shaped coordination arising from bonding to the N atom of three N-heterocycles; the geometry is distorted towards square pyramidal owing to two weak Ag⋯O(nitrate) inter­actions [Ag⋯O = 2.691 (5) and 3.073 (5) Å]. The cation and anion are linked by O—H⋯N and N—H⋯O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588784/ /pubmed/23468749 http://dx.doi.org/10.1107/S1600536812046119 Text en © Gao and Ng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Shan
Ng, Seik Weng
Tris{2-[(pyrimidin-2-yl-κN)amino­meth­yl]phenol}silver(I) nitrate
title Tris{2-[(pyrimidin-2-yl-κN)amino­meth­yl]phenol}silver(I) nitrate
title_full Tris{2-[(pyrimidin-2-yl-κN)amino­meth­yl]phenol}silver(I) nitrate
title_fullStr Tris{2-[(pyrimidin-2-yl-κN)amino­meth­yl]phenol}silver(I) nitrate
title_full_unstemmed Tris{2-[(pyrimidin-2-yl-κN)amino­meth­yl]phenol}silver(I) nitrate
title_short Tris{2-[(pyrimidin-2-yl-κN)amino­meth­yl]phenol}silver(I) nitrate
title_sort tris{2-[(pyrimidin-2-yl-κn)amino­meth­yl]phenol}silver(i) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588784/
https://www.ncbi.nlm.nih.gov/pubmed/23468749
http://dx.doi.org/10.1107/S1600536812046119
work_keys_str_mv AT gaoshan tris2pyrimidin2ylknaminomethylphenolsilverinitrate
AT ngseikweng tris2pyrimidin2ylknaminomethylphenolsilverinitrate

Ejemplares similares