Dimeth­yl(1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)tin(IV)

The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(NCS)(2)(C(12)H(8)N(2))], is located on a twofold rotation axis in a distorted octa­hedral enviroment. The methyl groups are trans to each other [C—Sn—C = 175.7 (3)°], whereas the thio­cyanate groups are cis to each other.

Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588785/
https://www.ncbi.nlm.nih.gov/pubmed/23468750
http://dx.doi.org/10.1107/S1600536812047691
Descripción
Sumario:The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(NCS)(2)(C(12)H(8)N(2))], is located on a twofold rotation axis in a distorted octa­hedral enviroment. The methyl groups are trans to each other [C—Sn—C = 175.7 (3)°], whereas the thio­cyanate groups are cis to each other.

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