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Di-μ(2)-isopropanolato-octamethylbis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazol-1-ido-κ(2) N (1):N (2))di-μ(3)-oxido-tetratin(IV)
The tetranuclear title compound, [Sn(4)(CH(3))(8)(C(3)H(7)O)(2)O(2)(C(3)H(4)N(3)S)(2)], lies about a center of inversion; the molecule features a three-rung-staircase Sn(4)O(4) core in which two Sn(IV) atoms are bridged by the 4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazol-1-ide group. The...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588787/ https://www.ncbi.nlm.nih.gov/pubmed/23468752 http://dx.doi.org/10.1107/S160053681204771X |
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author | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
author_facet | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
author_sort | Najafi, Ezzatollah |
collection | PubMed |
description | The tetranuclear title compound, [Sn(4)(CH(3))(8)(C(3)H(7)O)(2)O(2)(C(3)H(4)N(3)S)(2)], lies about a center of inversion; the molecule features a three-rung-staircase Sn(4)O(4) core in which two Sn(IV) atoms are bridged by the 4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazol-1-ide group. The negatively charged N atom of the group binds to the terminal Sn(IV) atom at a shorter distance [Sn—N = 2.236 (2) Å] compared with the neutral N atom that binds to the central Sn(IV) atom [Sn← N = 2.805 (2) Å]. The terminal Sn(IV) atom is five-coordinate in a cis-C(2)SnNO(2) trigonal–bipyramidal geometry [C—Sn—C = 136.4 (1)°], whereas the central Sn(IV) atom is six-coordinate in a C(2)SnNO(3) skew-trazepoidal bipyramidal geometry [C—Sn—C = 145.4 (1)°]. The C atoms of the isopropoxy group are disordered over two positions in a 0.591 (7):0.409 (7) ratio. |
format | Online Article Text |
id | pubmed-3588787 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887872013-03-06 Di-μ(2)-isopropanolato-octamethylbis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazol-1-ido-κ(2) N (1):N (2))di-μ(3)-oxido-tetratin(IV) Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The tetranuclear title compound, [Sn(4)(CH(3))(8)(C(3)H(7)O)(2)O(2)(C(3)H(4)N(3)S)(2)], lies about a center of inversion; the molecule features a three-rung-staircase Sn(4)O(4) core in which two Sn(IV) atoms are bridged by the 4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazol-1-ide group. The negatively charged N atom of the group binds to the terminal Sn(IV) atom at a shorter distance [Sn—N = 2.236 (2) Å] compared with the neutral N atom that binds to the central Sn(IV) atom [Sn← N = 2.805 (2) Å]. The terminal Sn(IV) atom is five-coordinate in a cis-C(2)SnNO(2) trigonal–bipyramidal geometry [C—Sn—C = 136.4 (1)°], whereas the central Sn(IV) atom is six-coordinate in a C(2)SnNO(3) skew-trazepoidal bipyramidal geometry [C—Sn—C = 145.4 (1)°]. The C atoms of the isopropoxy group are disordered over two positions in a 0.591 (7):0.409 (7) ratio. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588787/ /pubmed/23468752 http://dx.doi.org/10.1107/S160053681204771X Text en © Najafi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Di-μ(2)-isopropanolato-octamethylbis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazol-1-ido-κ(2) N (1):N (2))di-μ(3)-oxido-tetratin(IV) |
title | Di-μ(2)-isopropanolato-octamethylbis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazol-1-ido-κ(2)
N
(1):N
(2))di-μ(3)-oxido-tetratin(IV) |
title_full | Di-μ(2)-isopropanolato-octamethylbis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazol-1-ido-κ(2)
N
(1):N
(2))di-μ(3)-oxido-tetratin(IV) |
title_fullStr | Di-μ(2)-isopropanolato-octamethylbis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazol-1-ido-κ(2)
N
(1):N
(2))di-μ(3)-oxido-tetratin(IV) |
title_full_unstemmed | Di-μ(2)-isopropanolato-octamethylbis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazol-1-ido-κ(2)
N
(1):N
(2))di-μ(3)-oxido-tetratin(IV) |
title_short | Di-μ(2)-isopropanolato-octamethylbis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazol-1-ido-κ(2)
N
(1):N
(2))di-μ(3)-oxido-tetratin(IV) |
title_sort | di-μ(2)-isopropanolato-octamethylbis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1h-1,2,4-triazol-1-ido-κ(2)
n
(1):n
(2))di-μ(3)-oxido-tetratin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588787/ https://www.ncbi.nlm.nih.gov/pubmed/23468752 http://dx.doi.org/10.1107/S160053681204771X |
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