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Bis[μ-(E)-N-(pyridin-3-yl­methyl­idene)hy­droxy­amine]-κ(2) N (1):N (3);κ(2) N (3):N (1)-bis­{[(E)-N-(pyridin-3-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)} dinitrate

In the centrosymmetric dinuclear title Ag(I) compound, [Ag(2)(C(6)H(6)N(2)O)(4)](NO(3))(2), the aromatic amine-coordinated Ag(I) atom is further bridged by two hydroxyl­amine mol­ecules that use aromatic and oxime N atoms for bridging, and it exists in a distorted trigonal-planar geometry. In the cr...

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Detalles Bibliográficos
Autores principales: Gao, Shan, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588788/
https://www.ncbi.nlm.nih.gov/pubmed/23468753
http://dx.doi.org/10.1107/S1600536812045898
Descripción
Sumario:In the centrosymmetric dinuclear title Ag(I) compound, [Ag(2)(C(6)H(6)N(2)O)(4)](NO(3))(2), the aromatic amine-coordinated Ag(I) atom is further bridged by two hydroxyl­amine mol­ecules that use aromatic and oxime N atoms for bridging, and it exists in a distorted trigonal-planar geometry. In the crystal, the nitrate anions link to the dinuclear compound mol­ecules via O—H⋯O hydrogen bonds, generating a chain running along the a-axis direction.