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Bis[μ-(E)-N-(pyridin-3-ylmethylidene)hydroxyamine]-κ(2) N (1):N (3);κ(2) N (3):N (1)-bis{[(E)-N-(pyridin-3-ylmethylidene-κN)hydroxyamine]silver(I)} dinitrate
In the centrosymmetric dinuclear title Ag(I) compound, [Ag(2)(C(6)H(6)N(2)O)(4)](NO(3))(2), the aromatic amine-coordinated Ag(I) atom is further bridged by two hydroxylamine molecules that use aromatic and oxime N atoms for bridging, and it exists in a distorted trigonal-planar geometry. In the cr...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588788/ https://www.ncbi.nlm.nih.gov/pubmed/23468753 http://dx.doi.org/10.1107/S1600536812045898 |
Sumario: | In the centrosymmetric dinuclear title Ag(I) compound, [Ag(2)(C(6)H(6)N(2)O)(4)](NO(3))(2), the aromatic amine-coordinated Ag(I) atom is further bridged by two hydroxylamine molecules that use aromatic and oxime N atoms for bridging, and it exists in a distorted trigonal-planar geometry. In the crystal, the nitrate anions link to the dinuclear compound molecules via O—H⋯O hydrogen bonds, generating a chain running along the a-axis direction. |
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