Bis[μ-(E)-N-(pyridin-3-yl­methyl­idene)hy­droxy­amine]-κ(2) N (1):N (3);κ(2) N (3):N (1)-bis­{[(E)-N-(pyridin-3-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)} dinitrate

In the centrosymmetric dinuclear title Ag(I) compound, [Ag(2)(C(6)H(6)N(2)O)(4)](NO(3))(2), the aromatic amine-coordinated Ag(I) atom is further bridged by two hydroxyl­amine mol­ecules that use aromatic and oxime N atoms for bridging, and it exists in a distorted trigonal-planar geometry. In the cr...

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Detalles Bibliográficos
Autores principales: Gao, Shan, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588788/
https://www.ncbi.nlm.nih.gov/pubmed/23468753
http://dx.doi.org/10.1107/S1600536812045898
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author Gao, Shan
Ng, Seik Weng
author_facet Gao, Shan
Ng, Seik Weng
author_sort Gao, Shan
collection PubMed
description In the centrosymmetric dinuclear title Ag(I) compound, [Ag(2)(C(6)H(6)N(2)O)(4)](NO(3))(2), the aromatic amine-coordinated Ag(I) atom is further bridged by two hydroxyl­amine mol­ecules that use aromatic and oxime N atoms for bridging, and it exists in a distorted trigonal-planar geometry. In the crystal, the nitrate anions link to the dinuclear compound mol­ecules via O—H⋯O hydrogen bonds, generating a chain running along the a-axis direction.
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spelling pubmed-35887882013-03-06 Bis[μ-(E)-N-(pyridin-3-yl­methyl­idene)hy­droxy­amine]-κ(2) N (1):N (3);κ(2) N (3):N (1)-bis­{[(E)-N-(pyridin-3-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)} dinitrate Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title Ag(I) compound, [Ag(2)(C(6)H(6)N(2)O)(4)](NO(3))(2), the aromatic amine-coordinated Ag(I) atom is further bridged by two hydroxyl­amine mol­ecules that use aromatic and oxime N atoms for bridging, and it exists in a distorted trigonal-planar geometry. In the crystal, the nitrate anions link to the dinuclear compound mol­ecules via O—H⋯O hydrogen bonds, generating a chain running along the a-axis direction. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588788/ /pubmed/23468753 http://dx.doi.org/10.1107/S1600536812045898 Text en © Gao and Ng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Shan
Ng, Seik Weng
Bis[μ-(E)-N-(pyridin-3-yl­methyl­idene)hy­droxy­amine]-κ(2) N (1):N (3);κ(2) N (3):N (1)-bis­{[(E)-N-(pyridin-3-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)} dinitrate
title Bis[μ-(E)-N-(pyridin-3-yl­methyl­idene)hy­droxy­amine]-κ(2) N (1):N (3);κ(2) N (3):N (1)-bis­{[(E)-N-(pyridin-3-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)} dinitrate
title_full Bis[μ-(E)-N-(pyridin-3-yl­methyl­idene)hy­droxy­amine]-κ(2) N (1):N (3);κ(2) N (3):N (1)-bis­{[(E)-N-(pyridin-3-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)} dinitrate
title_fullStr Bis[μ-(E)-N-(pyridin-3-yl­methyl­idene)hy­droxy­amine]-κ(2) N (1):N (3);κ(2) N (3):N (1)-bis­{[(E)-N-(pyridin-3-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)} dinitrate
title_full_unstemmed Bis[μ-(E)-N-(pyridin-3-yl­methyl­idene)hy­droxy­amine]-κ(2) N (1):N (3);κ(2) N (3):N (1)-bis­{[(E)-N-(pyridin-3-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)} dinitrate
title_short Bis[μ-(E)-N-(pyridin-3-yl­methyl­idene)hy­droxy­amine]-κ(2) N (1):N (3);κ(2) N (3):N (1)-bis­{[(E)-N-(pyridin-3-yl­methyl­idene-κN)hy­droxy­amine]­silver(I)} dinitrate
title_sort bis[μ-(e)-n-(pyridin-3-yl­methyl­idene)hy­droxy­amine]-κ(2) n (1):n (3);κ(2) n (3):n (1)-bis­{[(e)-n-(pyridin-3-yl­methyl­idene-κn)hy­droxy­amine]­silver(i)} dinitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588788/
https://www.ncbi.nlm.nih.gov/pubmed/23468753
http://dx.doi.org/10.1107/S1600536812045898
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AT ngseikweng bismenpyridin3ylmethylidenehydroxyaminek2n1n3k2n3n1bisenpyridin3ylmethylideneknhydroxyaminesilveridinitrate

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