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[μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ(2) N (1):N (4)]bis[trimethyl(thiocyanato-κN)tin(IV)]
In the title compound, [Sn(2)(CH(3))(6)(NCS)(2)(C(24)H(22)N(4))], the 1,2,3,4-tetrakis(pyridin-4-yl)butane ligand uses the pyridine N atoms at the ends of the butyl chain to coordinate to two trimethylthiocyanatotin(IV) units, forming a dinuclear structure. The Sn(IV) atom in the molecule shows a...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588790/ https://www.ncbi.nlm.nih.gov/pubmed/23468755 http://dx.doi.org/10.1107/S160053681204737X |
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author | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
author_facet | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
author_sort | Najafi, Ezzatollah |
collection | PubMed |
description | In the title compound, [Sn(2)(CH(3))(6)(NCS)(2)(C(24)H(22)N(4))], the 1,2,3,4-tetrakis(pyridin-4-yl)butane ligand uses the pyridine N atoms at the ends of the butyl chain to coordinate to two trimethylthiocyanatotin(IV) units, forming a dinuclear structure. The Sn(IV) atom in the molecule shows a distorted trans-trigonal–bipyramidal coordination with the methyl groups in equatorial positions. The molecule lies on a center of inversion, with the mid-point of the butyl chain coinciding with this symmetry element. In the crystal, weak C—H⋯π interactions occur between pyridine rings of adjacent molecules. |
format | Online Article Text |
id | pubmed-3588790 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887902013-03-06 [μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ(2) N (1):N (4)]bis[trimethyl(thiocyanato-κN)tin(IV)] Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(2)(CH(3))(6)(NCS)(2)(C(24)H(22)N(4))], the 1,2,3,4-tetrakis(pyridin-4-yl)butane ligand uses the pyridine N atoms at the ends of the butyl chain to coordinate to two trimethylthiocyanatotin(IV) units, forming a dinuclear structure. The Sn(IV) atom in the molecule shows a distorted trans-trigonal–bipyramidal coordination with the methyl groups in equatorial positions. The molecule lies on a center of inversion, with the mid-point of the butyl chain coinciding with this symmetry element. In the crystal, weak C—H⋯π interactions occur between pyridine rings of adjacent molecules. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588790/ /pubmed/23468755 http://dx.doi.org/10.1107/S160053681204737X Text en © Najafi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng [μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ(2) N (1):N (4)]bis[trimethyl(thiocyanato-κN)tin(IV)] |
title | [μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ(2)
N
(1):N
(4)]bis[trimethyl(thiocyanato-κN)tin(IV)] |
title_full | [μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ(2)
N
(1):N
(4)]bis[trimethyl(thiocyanato-κN)tin(IV)] |
title_fullStr | [μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ(2)
N
(1):N
(4)]bis[trimethyl(thiocyanato-κN)tin(IV)] |
title_full_unstemmed | [μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ(2)
N
(1):N
(4)]bis[trimethyl(thiocyanato-κN)tin(IV)] |
title_short | [μ-1,2,3,4-Tetrakis(pyridin-4-yl)butane-κ(2)
N
(1):N
(4)]bis[trimethyl(thiocyanato-κN)tin(IV)] |
title_sort | [μ-1,2,3,4-tetrakis(pyridin-4-yl)butane-κ(2)
n
(1):n
(4)]bis[trimethyl(thiocyanato-κn)tin(iv)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588790/ https://www.ncbi.nlm.nih.gov/pubmed/23468755 http://dx.doi.org/10.1107/S160053681204737X |
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