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[μ-1,2,3,4-Tetra­kis(pyridin-4-yl)butane-κ(2) N (1):N (4)]bis­[trimeth­yl(thio­cyanato-κN)tin(IV)]

In the title compound, [Sn(2)(CH(3))(6)(NCS)(2)(C(24)H(22)N(4))], the 1,2,3,4-tetra­kis­(pyridin-4-yl)butane ligand uses the pyridine N atoms at the ends of the butyl chain to coordinate to two trimethylthiocyanatotin(IV) units, forming a dinuclear structure. The Sn(IV) atom in the mol­ecule shows a...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588790/
https://www.ncbi.nlm.nih.gov/pubmed/23468755
http://dx.doi.org/10.1107/S160053681204737X
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author Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Najafi, Ezzatollah
collection PubMed
description In the title compound, [Sn(2)(CH(3))(6)(NCS)(2)(C(24)H(22)N(4))], the 1,2,3,4-tetra­kis­(pyridin-4-yl)butane ligand uses the pyridine N atoms at the ends of the butyl chain to coordinate to two trimethylthiocyanatotin(IV) units, forming a dinuclear structure. The Sn(IV) atom in the mol­ecule shows a distorted trans-trigonal–bipyramidal coordination with the methyl groups in equatorial positions. The mol­ecule lies on a center of inversion, with the mid-point of the butyl chain coinciding with this symmetry element. In the crystal, weak C—H⋯π inter­actions occur between pyridine rings of adjacent mol­ecules.
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spelling pubmed-35887902013-03-06 [μ-1,2,3,4-Tetra­kis(pyridin-4-yl)butane-κ(2) N (1):N (4)]bis­[trimeth­yl(thio­cyanato-κN)tin(IV)] Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(2)(CH(3))(6)(NCS)(2)(C(24)H(22)N(4))], the 1,2,3,4-tetra­kis­(pyridin-4-yl)butane ligand uses the pyridine N atoms at the ends of the butyl chain to coordinate to two trimethylthiocyanatotin(IV) units, forming a dinuclear structure. The Sn(IV) atom in the mol­ecule shows a distorted trans-trigonal–bipyramidal coordination with the methyl groups in equatorial positions. The mol­ecule lies on a center of inversion, with the mid-point of the butyl chain coinciding with this symmetry element. In the crystal, weak C—H⋯π inter­actions occur between pyridine rings of adjacent mol­ecules. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588790/ /pubmed/23468755 http://dx.doi.org/10.1107/S160053681204737X Text en © Najafi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
[μ-1,2,3,4-Tetra­kis(pyridin-4-yl)butane-κ(2) N (1):N (4)]bis­[trimeth­yl(thio­cyanato-κN)tin(IV)]
title [μ-1,2,3,4-Tetra­kis(pyridin-4-yl)butane-κ(2) N (1):N (4)]bis­[trimeth­yl(thio­cyanato-κN)tin(IV)]
title_full [μ-1,2,3,4-Tetra­kis(pyridin-4-yl)butane-κ(2) N (1):N (4)]bis­[trimeth­yl(thio­cyanato-κN)tin(IV)]
title_fullStr [μ-1,2,3,4-Tetra­kis(pyridin-4-yl)butane-κ(2) N (1):N (4)]bis­[trimeth­yl(thio­cyanato-κN)tin(IV)]
title_full_unstemmed [μ-1,2,3,4-Tetra­kis(pyridin-4-yl)butane-κ(2) N (1):N (4)]bis­[trimeth­yl(thio­cyanato-κN)tin(IV)]
title_short [μ-1,2,3,4-Tetra­kis(pyridin-4-yl)butane-κ(2) N (1):N (4)]bis­[trimeth­yl(thio­cyanato-κN)tin(IV)]
title_sort [μ-1,2,3,4-tetra­kis(pyridin-4-yl)butane-κ(2) n (1):n (4)]bis­[trimeth­yl(thio­cyanato-κn)tin(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588790/
https://www.ncbi.nlm.nih.gov/pubmed/23468755
http://dx.doi.org/10.1107/S160053681204737X
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