Dimethyl­bis­(2-methyl­quinolin-8-olato-κ(2) N,O)tin(IV)

The Sn(IV) cation in the title compound, [Sn(CH(3))(2)(C(10)H(8)NO)(2)], is N,O-chelated by two 2-methyl­quinolin-8-olate anions and coordinated by two methyl groups in a skew-trapezoidal bipyramidal geometry. In the mol­ecule, the two quinoline ring systems are twisted to one another at 10.91 (18)°...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588791/
https://www.ncbi.nlm.nih.gov/pubmed/23468756
http://dx.doi.org/10.1107/S1600536812047393
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author Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Najafi, Ezzatollah
collection PubMed
description The Sn(IV) cation in the title compound, [Sn(CH(3))(2)(C(10)H(8)NO)(2)], is N,O-chelated by two 2-methyl­quinolin-8-olate anions and coordinated by two methyl groups in a skew-trapezoidal bipyramidal geometry. In the mol­ecule, the two quinoline ring systems are twisted to one another at 10.91 (18)°. The dimethyl­tin skeleton [C—Sn—C = 149.6 (2)°] is bent over the longer edge of the trapezoid that is defined by the four chelating atoms. Weak inter­molecular C—H⋯O hydrogen bonding occurs in the crystal.
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spelling pubmed-35887912013-03-06 Dimethyl­bis­(2-methyl­quinolin-8-olato-κ(2) N,O)tin(IV) Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) cation in the title compound, [Sn(CH(3))(2)(C(10)H(8)NO)(2)], is N,O-chelated by two 2-methyl­quinolin-8-olate anions and coordinated by two methyl groups in a skew-trapezoidal bipyramidal geometry. In the mol­ecule, the two quinoline ring systems are twisted to one another at 10.91 (18)°. The dimethyl­tin skeleton [C—Sn—C = 149.6 (2)°] is bent over the longer edge of the trapezoid that is defined by the four chelating atoms. Weak inter­molecular C—H⋯O hydrogen bonding occurs in the crystal. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588791/ /pubmed/23468756 http://dx.doi.org/10.1107/S1600536812047393 Text en © Najafi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
Dimethyl­bis­(2-methyl­quinolin-8-olato-κ(2) N,O)tin(IV)
title Dimethyl­bis­(2-methyl­quinolin-8-olato-κ(2) N,O)tin(IV)
title_full Dimethyl­bis­(2-methyl­quinolin-8-olato-κ(2) N,O)tin(IV)
title_fullStr Dimethyl­bis­(2-methyl­quinolin-8-olato-κ(2) N,O)tin(IV)
title_full_unstemmed Dimethyl­bis­(2-methyl­quinolin-8-olato-κ(2) N,O)tin(IV)
title_short Dimethyl­bis­(2-methyl­quinolin-8-olato-κ(2) N,O)tin(IV)
title_sort dimethyl­bis­(2-methyl­quinolin-8-olato-κ(2) n,o)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588791/
https://www.ncbi.nlm.nih.gov/pubmed/23468756
http://dx.doi.org/10.1107/S1600536812047393
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