trans-Tris(4-bromo­phen­yl)dichlorido­antimony(V)

The Sb(V) atom in the title compound, [SbCl(2)(C(6)H(4)Br)(3)], has an almost regular trigonal–bipyramidal geometry with the equatorial plane made up of three C atoms of the bromo­phenyl groups and the axial positions occupied by two Cl(−) ions in a trans configuration. In the crystal, C—H⋯Br hydrog...

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Detalles Bibliográficos
Autores principales: Qiao, Yanling, Jiang, Jin, Cui, Jichun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588792/
https://www.ncbi.nlm.nih.gov/pubmed/23468757
http://dx.doi.org/10.1107/S160053681204809X
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author Qiao, Yanling
Jiang, Jin
Cui, Jichun
author_facet Qiao, Yanling
Jiang, Jin
Cui, Jichun
author_sort Qiao, Yanling
collection PubMed
description The Sb(V) atom in the title compound, [SbCl(2)(C(6)H(4)Br)(3)], has an almost regular trigonal–bipyramidal geometry with the equatorial plane made up of three C atoms of the bromo­phenyl groups and the axial positions occupied by two Cl(−) ions in a trans configuration. In the crystal, C—H⋯Br hydrogen bonds link the mol­ecules into zigzag chains along the b-axis direction. Pairs of C—H⋯Cl hydrogen bonds further link mol­ecules into cyclic dimers with R (2) (2)(10) ring motifs, generating a three-dimensional network.
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spelling pubmed-35887922013-03-06 trans-Tris(4-bromo­phen­yl)dichlorido­antimony(V) Qiao, Yanling Jiang, Jin Cui, Jichun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sb(V) atom in the title compound, [SbCl(2)(C(6)H(4)Br)(3)], has an almost regular trigonal–bipyramidal geometry with the equatorial plane made up of three C atoms of the bromo­phenyl groups and the axial positions occupied by two Cl(−) ions in a trans configuration. In the crystal, C—H⋯Br hydrogen bonds link the mol­ecules into zigzag chains along the b-axis direction. Pairs of C—H⋯Cl hydrogen bonds further link mol­ecules into cyclic dimers with R (2) (2)(10) ring motifs, generating a three-dimensional network. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588792/ /pubmed/23468757 http://dx.doi.org/10.1107/S160053681204809X Text en © Qiao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Qiao, Yanling
Jiang, Jin
Cui, Jichun
trans-Tris(4-bromo­phen­yl)dichlorido­antimony(V)
title trans-Tris(4-bromo­phen­yl)dichlorido­antimony(V)
title_full trans-Tris(4-bromo­phen­yl)dichlorido­antimony(V)
title_fullStr trans-Tris(4-bromo­phen­yl)dichlorido­antimony(V)
title_full_unstemmed trans-Tris(4-bromo­phen­yl)dichlorido­antimony(V)
title_short trans-Tris(4-bromo­phen­yl)dichlorido­antimony(V)
title_sort trans-tris(4-bromo­phen­yl)dichlorido­antimony(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588792/
https://www.ncbi.nlm.nih.gov/pubmed/23468757
http://dx.doi.org/10.1107/S160053681204809X
work_keys_str_mv AT qiaoyanling transtris4bromophenyldichloridoantimonyv
AT jiangjin transtris4bromophenyldichloridoantimonyv
AT cuijichun transtris4bromophenyldichloridoantimonyv

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