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Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate
In the title compound, [Cu(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Cu(II) ion is bonded to two chelating 1,10-phenanthroline (phen) ligands and one O atom from a monodentate sulfate ligand in a distorted square-based pyramidal arrangement, with the O atom in a basal site. The two chelating N(2)C...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588794/ https://www.ncbi.nlm.nih.gov/pubmed/23468759 http://dx.doi.org/10.1107/S1600536812047721 |
Sumario: | In the title compound, [Cu(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Cu(II) ion is bonded to two chelating 1,10-phenanthroline (phen) ligands and one O atom from a monodentate sulfate ligand in a distorted square-based pyramidal arrangement, with the O atom in a basal site. The two chelating N(2)C(2) groups subtend a dihedral angle of 71.10 (15)°. In the crystal, the solvent molecule forms two O—H⋯O hydrogen bonds to its adjacent complex molecule. The chosen crystal was found to be a racemic twin; the presence of pseudosymmetry in the structure suggests the higher symmetry space group C2/c, but attempts to refine the structure in this space group resulted in an unsatisfactory model and high R and wR values. |
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