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Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate

In the title compound, [Cu(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Cu(II) ion is bonded to two chelating 1,10-phenanthroline (phen) ligands and one O atom from a monodentate sulfate ligand in a distorted square-based pyramidal arrangement, with the O atom in a basal site. The two chelating N(2)C...

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Autor principal: Zhong, Kai-Long
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588794/
https://www.ncbi.nlm.nih.gov/pubmed/23468759
http://dx.doi.org/10.1107/S1600536812047721
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author Zhong, Kai-Long
author_facet Zhong, Kai-Long
author_sort Zhong, Kai-Long
collection PubMed
description In the title compound, [Cu(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Cu(II) ion is bonded to two chelating 1,10-phenanthroline (phen) ligands and one O atom from a monodentate sulfate ligand in a distorted square-based pyramidal arrangement, with the O atom in a basal site. The two chelating N(2)C(2) groups subtend a dihedral angle of 71.10 (15)°. In the crystal, the solvent mol­ecule forms two O—H⋯O hydrogen bonds to its adjacent complex mol­ecule. The chosen crystal was found to be a racemic twin; the presence of pseudosymmetry in the structure suggests the higher symmetry space group C2/c, but attempts to refine the structure in this space group resulted in an unsatisfactory model and high R and wR values.
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spelling pubmed-35887942013-03-06 Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate Zhong, Kai-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Cu(II) ion is bonded to two chelating 1,10-phenanthroline (phen) ligands and one O atom from a monodentate sulfate ligand in a distorted square-based pyramidal arrangement, with the O atom in a basal site. The two chelating N(2)C(2) groups subtend a dihedral angle of 71.10 (15)°. In the crystal, the solvent mol­ecule forms two O—H⋯O hydrogen bonds to its adjacent complex mol­ecule. The chosen crystal was found to be a racemic twin; the presence of pseudosymmetry in the structure suggests the higher symmetry space group C2/c, but attempts to refine the structure in this space group resulted in an unsatisfactory model and high R and wR values. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588794/ /pubmed/23468759 http://dx.doi.org/10.1107/S1600536812047721 Text en © Kai-Long Zhong 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhong, Kai-Long
Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate
title Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate
title_full Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate
title_fullStr Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate
title_full_unstemmed Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate
title_short Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate
title_sort bis(1,10-phenanthroline-κ(2) n,n′)(sulfato-o)copper(ii) propane-1,3-diol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588794/
https://www.ncbi.nlm.nih.gov/pubmed/23468759
http://dx.doi.org/10.1107/S1600536812047721
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