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Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate
In the title compound, [Cu(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Cu(II) ion is bonded to two chelating 1,10-phenanthroline (phen) ligands and one O atom from a monodentate sulfate ligand in a distorted square-based pyramidal arrangement, with the O atom in a basal site. The two chelating N(2)C...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588794/ https://www.ncbi.nlm.nih.gov/pubmed/23468759 http://dx.doi.org/10.1107/S1600536812047721 |
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author | Zhong, Kai-Long |
author_facet | Zhong, Kai-Long |
author_sort | Zhong, Kai-Long |
collection | PubMed |
description | In the title compound, [Cu(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Cu(II) ion is bonded to two chelating 1,10-phenanthroline (phen) ligands and one O atom from a monodentate sulfate ligand in a distorted square-based pyramidal arrangement, with the O atom in a basal site. The two chelating N(2)C(2) groups subtend a dihedral angle of 71.10 (15)°. In the crystal, the solvent molecule forms two O—H⋯O hydrogen bonds to its adjacent complex molecule. The chosen crystal was found to be a racemic twin; the presence of pseudosymmetry in the structure suggests the higher symmetry space group C2/c, but attempts to refine the structure in this space group resulted in an unsatisfactory model and high R and wR values. |
format | Online Article Text |
id | pubmed-3588794 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35887942013-03-06 Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate Zhong, Kai-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Cu(II) ion is bonded to two chelating 1,10-phenanthroline (phen) ligands and one O atom from a monodentate sulfate ligand in a distorted square-based pyramidal arrangement, with the O atom in a basal site. The two chelating N(2)C(2) groups subtend a dihedral angle of 71.10 (15)°. In the crystal, the solvent molecule forms two O—H⋯O hydrogen bonds to its adjacent complex molecule. The chosen crystal was found to be a racemic twin; the presence of pseudosymmetry in the structure suggests the higher symmetry space group C2/c, but attempts to refine the structure in this space group resulted in an unsatisfactory model and high R and wR values. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588794/ /pubmed/23468759 http://dx.doi.org/10.1107/S1600536812047721 Text en © Kai-Long Zhong 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhong, Kai-Long Bis(1,10-phenanthroline-κ(2) N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate |
title | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate |
title_full | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate |
title_fullStr | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate |
title_full_unstemmed | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate |
title_short | Bis(1,10-phenanthroline-κ(2)
N,N′)(sulfato-O)copper(II) propane-1,3-diol monosolvate |
title_sort | bis(1,10-phenanthroline-κ(2)
n,n′)(sulfato-o)copper(ii) propane-1,3-diol monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588794/ https://www.ncbi.nlm.nih.gov/pubmed/23468759 http://dx.doi.org/10.1107/S1600536812047721 |
work_keys_str_mv | AT zhongkailong bis110phenanthrolinek2nnsulfatoocopperiipropane13diolmonosolvate |