Tricarbonyl­bis­(1,3-diisopropyl-4,5-dimethyl­imidazol-2-yl­idene)iron

In the title compound, [Fe(C(11)H(20)N(2))(2)(CO)(3)], the Fe atom shows a distorted trigonal–bipyramidal geometry with three carbonyl and two carbene ligands. The latter have a cis arrangement, with a C—Fe—C angle of 90.60 (7)°. The Fe atom lies 0.007 (1) Å above the basal plane defined by two carb...

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Detalles Bibliográficos
Autores principales: Ahmida, Aziza, Flörke, Ulrich, Henkel, Gerald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588795/
https://www.ncbi.nlm.nih.gov/pubmed/23468760
http://dx.doi.org/10.1107/S1600536812048179
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author Ahmida, Aziza
Flörke, Ulrich
Henkel, Gerald
author_facet Ahmida, Aziza
Flörke, Ulrich
Henkel, Gerald
author_sort Ahmida, Aziza
collection PubMed
description In the title compound, [Fe(C(11)H(20)N(2))(2)(CO)(3)], the Fe atom shows a distorted trigonal–bipyramidal geometry with three carbonyl and two carbene ligands. The latter have a cis arrangement, with a C—Fe—C angle of 90.60 (7)°. The Fe atom lies 0.007 (1) Å above the basal plane defined by two carbonyl and one carbene C atoms. The mol­ecular structure is closely related to that of the isomolecular but not isotypic Ru complex with an identical cis arrangement, so, in general, bond geometries lie in expected ranges. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into infinite zigzag chains extending along [010].
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spelling pubmed-35887952013-03-06 Tricarbonyl­bis­(1,3-diisopropyl-4,5-dimethyl­imidazol-2-yl­idene)iron Ahmida, Aziza Flörke, Ulrich Henkel, Gerald Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(11)H(20)N(2))(2)(CO)(3)], the Fe atom shows a distorted trigonal–bipyramidal geometry with three carbonyl and two carbene ligands. The latter have a cis arrangement, with a C—Fe—C angle of 90.60 (7)°. The Fe atom lies 0.007 (1) Å above the basal plane defined by two carbonyl and one carbene C atoms. The mol­ecular structure is closely related to that of the isomolecular but not isotypic Ru complex with an identical cis arrangement, so, in general, bond geometries lie in expected ranges. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into infinite zigzag chains extending along [010]. International Union of Crystallography 2012-11-28 /pmc/articles/PMC3588795/ /pubmed/23468760 http://dx.doi.org/10.1107/S1600536812048179 Text en © Ahmida et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ahmida, Aziza
Flörke, Ulrich
Henkel, Gerald
Tricarbonyl­bis­(1,3-diisopropyl-4,5-dimethyl­imidazol-2-yl­idene)iron
title Tricarbonyl­bis­(1,3-diisopropyl-4,5-dimethyl­imidazol-2-yl­idene)iron
title_full Tricarbonyl­bis­(1,3-diisopropyl-4,5-dimethyl­imidazol-2-yl­idene)iron
title_fullStr Tricarbonyl­bis­(1,3-diisopropyl-4,5-dimethyl­imidazol-2-yl­idene)iron
title_full_unstemmed Tricarbonyl­bis­(1,3-diisopropyl-4,5-dimethyl­imidazol-2-yl­idene)iron
title_short Tricarbonyl­bis­(1,3-diisopropyl-4,5-dimethyl­imidazol-2-yl­idene)iron
title_sort tricarbonyl­bis­(1,3-diisopropyl-4,5-dimethyl­imidazol-2-yl­idene)iron
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588795/
https://www.ncbi.nlm.nih.gov/pubmed/23468760
http://dx.doi.org/10.1107/S1600536812048179
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AT henkelgerald tricarbonylbis13diisopropyl45dimethylimidazol2ylideneiron

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