trans-Dichloridobis{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}platinum(II) dichloro­methane disolvate

In the title complex, trans-[PtCl(2){P(C(6)H(11))(2)(4-Me(2)NC(6)H(4))}(2)]·2CH(2)Cl(2), the Pt(II) atom is located on an inversion centre, resulting in a trans-square-planar geometry. Important geometric parameters are the Pt—P and Pt—Cl bond lengths of 2.3258 (6) and 2.3106 (6) Å, respectively, an...

Descripción completa

Detalles Bibliográficos
Autores principales: Davis, Wade L., Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588798/
https://www.ncbi.nlm.nih.gov/pubmed/23468763
http://dx.doi.org/10.1107/S1600536812048465
_version_ 1782261639511277568
author Davis, Wade L.
Meijboom, Reinout
author_facet Davis, Wade L.
Meijboom, Reinout
author_sort Davis, Wade L.
collection PubMed
description In the title complex, trans-[PtCl(2){P(C(6)H(11))(2)(4-Me(2)NC(6)H(4))}(2)]·2CH(2)Cl(2), the Pt(II) atom is located on an inversion centre, resulting in a trans-square-planar geometry. Important geometric parameters are the Pt—P and Pt—Cl bond lengths of 2.3258 (6) and 2.3106 (6) Å, respectively, and the P—Pt—Cl angles of 89.64 (2) and 90.36 (2)°. The effective cone angle for the dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane unit was calculated to be 164°. The compound crystallizes with two dichloro­methane solvent mol­ecules; one of which is severely disordered and was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155].
format Online
Article
Text
id pubmed-3588798
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35887982013-03-06 trans-Dichloridobis{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}platinum(II) dichloro­methane disolvate Davis, Wade L. Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, trans-[PtCl(2){P(C(6)H(11))(2)(4-Me(2)NC(6)H(4))}(2)]·2CH(2)Cl(2), the Pt(II) atom is located on an inversion centre, resulting in a trans-square-planar geometry. Important geometric parameters are the Pt—P and Pt—Cl bond lengths of 2.3258 (6) and 2.3106 (6) Å, respectively, and the P—Pt—Cl angles of 89.64 (2) and 90.36 (2)°. The effective cone angle for the dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane unit was calculated to be 164°. The compound crystallizes with two dichloro­methane solvent mol­ecules; one of which is severely disordered and was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]. International Union of Crystallography 2012-11-30 /pmc/articles/PMC3588798/ /pubmed/23468763 http://dx.doi.org/10.1107/S1600536812048465 Text en © Davis and Meijboom 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Davis, Wade L.
Meijboom, Reinout
trans-Dichloridobis{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}platinum(II) dichloro­methane disolvate
title trans-Dichloridobis{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}platinum(II) dichloro­methane disolvate
title_full trans-Dichloridobis{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}platinum(II) dichloro­methane disolvate
title_fullStr trans-Dichloridobis{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}platinum(II) dichloro­methane disolvate
title_full_unstemmed trans-Dichloridobis{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}platinum(II) dichloro­methane disolvate
title_short trans-Dichloridobis{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κP}platinum(II) dichloro­methane disolvate
title_sort trans-dichloridobis{dicyclo­hex­yl[4-(dimethyl­amino)­phen­yl]phosphane-κp}platinum(ii) dichloro­methane disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588798/
https://www.ncbi.nlm.nih.gov/pubmed/23468763
http://dx.doi.org/10.1107/S1600536812048465
work_keys_str_mv AT daviswadel transdichloridobisdicyclohexyl4dimethylaminophenylphosphanekpplatinumiidichloromethanedisolvate
AT meijboomreinout transdichloridobisdicyclohexyl4dimethylaminophenylphosphanekpplatinumiidichloromethanedisolvate

Ejemplares similares