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trans-Di-μ-chlorido-bis{chlorido[tris(3,5-dimethylphenyl)phosphane-κP]palladium(II)} dichloromethane monosolvate
In the dimeric title compound, [Pd(2)Cl(4){P(C(8)H(9))(3)}(2)]·CH(2)Cl(2), the metal complex molecule is situated about an inversion centre and is accompanied by a dichloromethane solvent molecule situated on a twofold rotation axis. The Pd(II) atom has a slightly distorted square-planar coordinat...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588800/ https://www.ncbi.nlm.nih.gov/pubmed/23468765 http://dx.doi.org/10.1107/S1600536812048556 |
Sumario: | In the dimeric title compound, [Pd(2)Cl(4){P(C(8)H(9))(3)}(2)]·CH(2)Cl(2), the metal complex molecule is situated about an inversion centre and is accompanied by a dichloromethane solvent molecule situated on a twofold rotation axis. The Pd(II) atom has a slightly distorted square-planar coordination sphere. The effective cone angle for the tris(3,5-dimethylphenyl)phosphane ligand was calculated to be 169°. In the crystal, the metal complex and solvent molecules are linked via C—H⋯Cl interactions, generating chains along [10-2]. There are also C—H⋯π and weak π–π interactions present [centroid–centroid distance = 3.990 (2) Å, plane–plane distance = 3.6352 (15) Å and ring slippage = 1.644 Å], forming of a three-dimensional structure. |
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