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trans-Di-μ-chlorido-bis{chlorido[tris(3,5-dimethylphenyl)phosphane-κP]palladium(II)} dichloromethane monosolvate
In the dimeric title compound, [Pd(2)Cl(4){P(C(8)H(9))(3)}(2)]·CH(2)Cl(2), the metal complex molecule is situated about an inversion centre and is accompanied by a dichloromethane solvent molecule situated on a twofold rotation axis. The Pd(II) atom has a slightly distorted square-planar coordinat...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588800/ https://www.ncbi.nlm.nih.gov/pubmed/23468765 http://dx.doi.org/10.1107/S1600536812048556 |
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author | Davis, Wade L. Muller, Alfred |
author_facet | Davis, Wade L. Muller, Alfred |
author_sort | Davis, Wade L. |
collection | PubMed |
description | In the dimeric title compound, [Pd(2)Cl(4){P(C(8)H(9))(3)}(2)]·CH(2)Cl(2), the metal complex molecule is situated about an inversion centre and is accompanied by a dichloromethane solvent molecule situated on a twofold rotation axis. The Pd(II) atom has a slightly distorted square-planar coordination sphere. The effective cone angle for the tris(3,5-dimethylphenyl)phosphane ligand was calculated to be 169°. In the crystal, the metal complex and solvent molecules are linked via C—H⋯Cl interactions, generating chains along [10-2]. There are also C—H⋯π and weak π–π interactions present [centroid–centroid distance = 3.990 (2) Å, plane–plane distance = 3.6352 (15) Å and ring slippage = 1.644 Å], forming of a three-dimensional structure. |
format | Online Article Text |
id | pubmed-3588800 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35888002013-03-06 trans-Di-μ-chlorido-bis{chlorido[tris(3,5-dimethylphenyl)phosphane-κP]palladium(II)} dichloromethane monosolvate Davis, Wade L. Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the dimeric title compound, [Pd(2)Cl(4){P(C(8)H(9))(3)}(2)]·CH(2)Cl(2), the metal complex molecule is situated about an inversion centre and is accompanied by a dichloromethane solvent molecule situated on a twofold rotation axis. The Pd(II) atom has a slightly distorted square-planar coordination sphere. The effective cone angle for the tris(3,5-dimethylphenyl)phosphane ligand was calculated to be 169°. In the crystal, the metal complex and solvent molecules are linked via C—H⋯Cl interactions, generating chains along [10-2]. There are also C—H⋯π and weak π–π interactions present [centroid–centroid distance = 3.990 (2) Å, plane–plane distance = 3.6352 (15) Å and ring slippage = 1.644 Å], forming of a three-dimensional structure. International Union of Crystallography 2012-11-30 /pmc/articles/PMC3588800/ /pubmed/23468765 http://dx.doi.org/10.1107/S1600536812048556 Text en © Davis and Muller 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Davis, Wade L. Muller, Alfred trans-Di-μ-chlorido-bis{chlorido[tris(3,5-dimethylphenyl)phosphane-κP]palladium(II)} dichloromethane monosolvate |
title |
trans-Di-μ-chlorido-bis{chlorido[tris(3,5-dimethylphenyl)phosphane-κP]palladium(II)} dichloromethane monosolvate |
title_full |
trans-Di-μ-chlorido-bis{chlorido[tris(3,5-dimethylphenyl)phosphane-κP]palladium(II)} dichloromethane monosolvate |
title_fullStr |
trans-Di-μ-chlorido-bis{chlorido[tris(3,5-dimethylphenyl)phosphane-κP]palladium(II)} dichloromethane monosolvate |
title_full_unstemmed |
trans-Di-μ-chlorido-bis{chlorido[tris(3,5-dimethylphenyl)phosphane-κP]palladium(II)} dichloromethane monosolvate |
title_short |
trans-Di-μ-chlorido-bis{chlorido[tris(3,5-dimethylphenyl)phosphane-κP]palladium(II)} dichloromethane monosolvate |
title_sort | trans-di-μ-chlorido-bis{chlorido[tris(3,5-dimethylphenyl)phosphane-κp]palladium(ii)} dichloromethane monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588800/ https://www.ncbi.nlm.nih.gov/pubmed/23468765 http://dx.doi.org/10.1107/S1600536812048556 |
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