Cargando…

trans-Di-μ-chlorido-bis­{chlorido[tris­(3,5-dimethyl­phen­yl)phosphane-κP]palla­dium(II)} dichloro­methane monosolvate

In the dimeric title compound, [Pd(2)Cl(4){P(C(8)H(9))(3)}(2)]·CH(2)Cl(2), the metal complex molecule is situated about an inversion centre and is accompanied by a dichloro­methane solvent mol­ecule situated on a twofold rotation axis. The Pd(II) atom has a slightly distorted square-planar coordinat...

Descripción completa

Detalles Bibliográficos
Autores principales: Davis, Wade L., Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588800/
https://www.ncbi.nlm.nih.gov/pubmed/23468765
http://dx.doi.org/10.1107/S1600536812048556
_version_ 1782261639993622528
author Davis, Wade L.
Muller, Alfred
author_facet Davis, Wade L.
Muller, Alfred
author_sort Davis, Wade L.
collection PubMed
description In the dimeric title compound, [Pd(2)Cl(4){P(C(8)H(9))(3)}(2)]·CH(2)Cl(2), the metal complex molecule is situated about an inversion centre and is accompanied by a dichloro­methane solvent mol­ecule situated on a twofold rotation axis. The Pd(II) atom has a slightly distorted square-planar coordination sphere. The effective cone angle for the tris­(3,5-dimethyl­phen­yl)phos­phane ligand was calculated to be 169°. In the crystal, the metal complex and solvent mol­ecules are linked via C—H⋯Cl inter­actions, generating chains along [10-2]. There are also C—H⋯π and weak π–π inter­actions present [centroid–centroid distance = 3.990 (2) Å, plane–plane distance = 3.6352 (15) Å and ring slippage = 1.644 Å], forming of a three-dimensional structure.
format Online
Article
Text
id pubmed-3588800
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35888002013-03-06 trans-Di-μ-chlorido-bis­{chlorido[tris­(3,5-dimethyl­phen­yl)phosphane-κP]palla­dium(II)} dichloro­methane monosolvate Davis, Wade L. Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the dimeric title compound, [Pd(2)Cl(4){P(C(8)H(9))(3)}(2)]·CH(2)Cl(2), the metal complex molecule is situated about an inversion centre and is accompanied by a dichloro­methane solvent mol­ecule situated on a twofold rotation axis. The Pd(II) atom has a slightly distorted square-planar coordination sphere. The effective cone angle for the tris­(3,5-dimethyl­phen­yl)phos­phane ligand was calculated to be 169°. In the crystal, the metal complex and solvent mol­ecules are linked via C—H⋯Cl inter­actions, generating chains along [10-2]. There are also C—H⋯π and weak π–π inter­actions present [centroid–centroid distance = 3.990 (2) Å, plane–plane distance = 3.6352 (15) Å and ring slippage = 1.644 Å], forming of a three-dimensional structure. International Union of Crystallography 2012-11-30 /pmc/articles/PMC3588800/ /pubmed/23468765 http://dx.doi.org/10.1107/S1600536812048556 Text en © Davis and Muller 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Davis, Wade L.
Muller, Alfred
trans-Di-μ-chlorido-bis­{chlorido[tris­(3,5-dimethyl­phen­yl)phosphane-κP]palla­dium(II)} dichloro­methane monosolvate
title trans-Di-μ-chlorido-bis­{chlorido[tris­(3,5-dimethyl­phen­yl)phosphane-κP]palla­dium(II)} dichloro­methane monosolvate
title_full trans-Di-μ-chlorido-bis­{chlorido[tris­(3,5-dimethyl­phen­yl)phosphane-κP]palla­dium(II)} dichloro­methane monosolvate
title_fullStr trans-Di-μ-chlorido-bis­{chlorido[tris­(3,5-dimethyl­phen­yl)phosphane-κP]palla­dium(II)} dichloro­methane monosolvate
title_full_unstemmed trans-Di-μ-chlorido-bis­{chlorido[tris­(3,5-dimethyl­phen­yl)phosphane-κP]palla­dium(II)} dichloro­methane monosolvate
title_short trans-Di-μ-chlorido-bis­{chlorido[tris­(3,5-dimethyl­phen­yl)phosphane-κP]palla­dium(II)} dichloro­methane monosolvate
title_sort trans-di-μ-chlorido-bis­{chlorido[tris­(3,5-dimethyl­phen­yl)phosphane-κp]palla­dium(ii)} dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588800/
https://www.ncbi.nlm.nih.gov/pubmed/23468765
http://dx.doi.org/10.1107/S1600536812048556
work_keys_str_mv AT daviswadel transdimchloridobischloridotris35dimethylphenylphosphanekppalladiumiidichloromethanemonosolvate
AT mulleralfred transdimchloridobischloridotris35dimethylphenylphosphanekppalladiumiidichloromethanemonosolvate