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Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ(2) C (1),P}palladium(II)) dichloromethane disolvate
The title compound, [Pd(2){P(C(10)H(7))(2)(C(10)H(6))}(2)Cl(2)]·2CH(2)Cl(2), shows cyclometalation of one naphthalen-1-yl substituent of each of the phosphane ligands to the Pd dimer in a trans orientation; the complete dimer is generated by a centre of inversion. Two dichloromethane solvent mole...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588801/ https://www.ncbi.nlm.nih.gov/pubmed/23468766 http://dx.doi.org/10.1107/S1600536812048222 |
Sumario: | The title compound, [Pd(2){P(C(10)H(7))(2)(C(10)H(6))}(2)Cl(2)]·2CH(2)Cl(2), shows cyclometalation of one naphthalen-1-yl substituent of each of the phosphane ligands to the Pd dimer in a trans orientation; the complete dimer is generated by a centre of inversion. Two dichloromethane solvent molecules create C—H⋯Cl interactions with the metal complex, generating supermolecular layers in the ab plane. Additional C—H⋯π and π–π [centroid–centroid distances = 3.713 (3), 3.850 (4) and 3.926 (3) Å] interactions join these planes into a three-dimensional supermolecular network. |
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