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Di-μ-chlorido-bis­({8-[bis­(naphthalen-1-yl)phosphan­yl]naphthalen-1-yl-κ(2) C (1),P}palladium(II)) dichloro­methane disolvate

The title compound, [Pd(2){P(C(10)H(7))(2)(C(10)H(6))}(2)Cl(2)]·2CH(2)Cl(2), shows cyclo­metalation of one naphthalen-1-yl substituent of each of the phosphane ligands to the Pd dimer in a trans orientation; the complete dimer is generated by a centre of inversion. Two dichloro­methane solvent mol­e...

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Detalles Bibliográficos
Autores principales: Davis, Wade L., Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588801/
https://www.ncbi.nlm.nih.gov/pubmed/23468766
http://dx.doi.org/10.1107/S1600536812048222
Descripción
Sumario:The title compound, [Pd(2){P(C(10)H(7))(2)(C(10)H(6))}(2)Cl(2)]·2CH(2)Cl(2), shows cyclo­metalation of one naphthalen-1-yl substituent of each of the phosphane ligands to the Pd dimer in a trans orientation; the complete dimer is generated by a centre of inversion. Two dichloro­methane solvent mol­ecules create C—H⋯Cl inter­actions with the metal complex, generating supermolecular layers in the ab plane. Additional C—H⋯π and π–π [centroid–centroid distances = 3.713 (3), 3.850 (4) and 3.926 (3) Å] inter­actions join these planes into a three-dimensional supermolecular network.