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Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ(2) C (1),P}palladium(II)) dichloromethane disolvate
The title compound, [Pd(2){P(C(10)H(7))(2)(C(10)H(6))}(2)Cl(2)]·2CH(2)Cl(2), shows cyclometalation of one naphthalen-1-yl substituent of each of the phosphane ligands to the Pd dimer in a trans orientation; the complete dimer is generated by a centre of inversion. Two dichloromethane solvent mole...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588801/ https://www.ncbi.nlm.nih.gov/pubmed/23468766 http://dx.doi.org/10.1107/S1600536812048222 |
| _version_ | 1782261640235843584 |
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| author | Davis, Wade L. Muller, Alfred |
| author_facet | Davis, Wade L. Muller, Alfred |
| author_sort | Davis, Wade L. |
| collection | PubMed |
| description | The title compound, [Pd(2){P(C(10)H(7))(2)(C(10)H(6))}(2)Cl(2)]·2CH(2)Cl(2), shows cyclometalation of one naphthalen-1-yl substituent of each of the phosphane ligands to the Pd dimer in a trans orientation; the complete dimer is generated by a centre of inversion. Two dichloromethane solvent molecules create C—H⋯Cl interactions with the metal complex, generating supermolecular layers in the ab plane. Additional C—H⋯π and π–π [centroid–centroid distances = 3.713 (3), 3.850 (4) and 3.926 (3) Å] interactions join these planes into a three-dimensional supermolecular network. |
| format | Online Article Text |
| id | pubmed-3588801 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35888012013-03-06 Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ(2) C (1),P}palladium(II)) dichloromethane disolvate Davis, Wade L. Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(2){P(C(10)H(7))(2)(C(10)H(6))}(2)Cl(2)]·2CH(2)Cl(2), shows cyclometalation of one naphthalen-1-yl substituent of each of the phosphane ligands to the Pd dimer in a trans orientation; the complete dimer is generated by a centre of inversion. Two dichloromethane solvent molecules create C—H⋯Cl interactions with the metal complex, generating supermolecular layers in the ab plane. Additional C—H⋯π and π–π [centroid–centroid distances = 3.713 (3), 3.850 (4) and 3.926 (3) Å] interactions join these planes into a three-dimensional supermolecular network. International Union of Crystallography 2012-11-30 /pmc/articles/PMC3588801/ /pubmed/23468766 http://dx.doi.org/10.1107/S1600536812048222 Text en © Davis and Muller 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Davis, Wade L. Muller, Alfred Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ(2) C (1),P}palladium(II)) dichloromethane disolvate |
| title | Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ(2)
C
(1),P}palladium(II)) dichloromethane disolvate |
| title_full | Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ(2)
C
(1),P}palladium(II)) dichloromethane disolvate |
| title_fullStr | Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ(2)
C
(1),P}palladium(II)) dichloromethane disolvate |
| title_full_unstemmed | Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ(2)
C
(1),P}palladium(II)) dichloromethane disolvate |
| title_short | Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ(2)
C
(1),P}palladium(II)) dichloromethane disolvate |
| title_sort | di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ(2)
c
(1),p}palladium(ii)) dichloromethane disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588801/ https://www.ncbi.nlm.nih.gov/pubmed/23468766 http://dx.doi.org/10.1107/S1600536812048222 |
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