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Diammine{N-[2-(hydroxyimino)propionyl]-N′-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ(4) N,N′,N′′,N′′′}iron(III)
In the title compound, [Fe(C(9)H(13)N(4)O(4))(NH(3))(2)], the Fe(III) atom, lying on a mirror plane, is coordinated by four N atoms of a triply deprotonated tetradentate N-[2-(hydroxyimino)propionyl]-N′-[2-(oxidoimino)propionyl]propane-1,3-diaminide ligand in the equatorial plane and two N at...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588803/ https://www.ncbi.nlm.nih.gov/pubmed/23468768 http://dx.doi.org/10.1107/S160053681204826X |
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author | Tomyn, Stefania Haukka, Matti Nedelkov, Ruslan |
author_facet | Tomyn, Stefania Haukka, Matti Nedelkov, Ruslan |
author_sort | Tomyn, Stefania |
collection | PubMed |
description | In the title compound, [Fe(C(9)H(13)N(4)O(4))(NH(3))(2)], the Fe(III) atom, lying on a mirror plane, is coordinated by four N atoms of a triply deprotonated tetradentate N-[2-(hydroxyimino)propionyl]-N′-[2-(oxidoimino)propionyl]propane-1,3-diaminide ligand in the equatorial plane and two N atoms of two ammonia molecules at the axial positions in a distorted octahedral geometry. A short intramolecular O—H⋯O hydrogen bond between the cis-disposed oxime O atoms stabilizes the pseudo-macrocyclic configuration of the ligand. In the crystal, molecules are linked by N—H⋯O hydrogen bonds into a three-dimensional network. The ligand has a mirror-plane symmetry. One of the methylene groups of the propane bridge is disordered over two sets of sites with equal occupancy factors. |
format | Online Article Text |
id | pubmed-3588803 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35888032013-03-06 Diammine{N-[2-(hydroxyimino)propionyl]-N′-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ(4) N,N′,N′′,N′′′}iron(III) Tomyn, Stefania Haukka, Matti Nedelkov, Ruslan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(9)H(13)N(4)O(4))(NH(3))(2)], the Fe(III) atom, lying on a mirror plane, is coordinated by four N atoms of a triply deprotonated tetradentate N-[2-(hydroxyimino)propionyl]-N′-[2-(oxidoimino)propionyl]propane-1,3-diaminide ligand in the equatorial plane and two N atoms of two ammonia molecules at the axial positions in a distorted octahedral geometry. A short intramolecular O—H⋯O hydrogen bond between the cis-disposed oxime O atoms stabilizes the pseudo-macrocyclic configuration of the ligand. In the crystal, molecules are linked by N—H⋯O hydrogen bonds into a three-dimensional network. The ligand has a mirror-plane symmetry. One of the methylene groups of the propane bridge is disordered over two sets of sites with equal occupancy factors. International Union of Crystallography 2012-11-30 /pmc/articles/PMC3588803/ /pubmed/23468768 http://dx.doi.org/10.1107/S160053681204826X Text en © Tomyn et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tomyn, Stefania Haukka, Matti Nedelkov, Ruslan Diammine{N-[2-(hydroxyimino)propionyl]-N′-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ(4) N,N′,N′′,N′′′}iron(III) |
title | Diammine{N-[2-(hydroxyimino)propionyl]-N′-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ(4)
N,N′,N′′,N′′′}iron(III) |
title_full | Diammine{N-[2-(hydroxyimino)propionyl]-N′-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ(4)
N,N′,N′′,N′′′}iron(III) |
title_fullStr | Diammine{N-[2-(hydroxyimino)propionyl]-N′-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ(4)
N,N′,N′′,N′′′}iron(III) |
title_full_unstemmed | Diammine{N-[2-(hydroxyimino)propionyl]-N′-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ(4)
N,N′,N′′,N′′′}iron(III) |
title_short | Diammine{N-[2-(hydroxyimino)propionyl]-N′-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ(4)
N,N′,N′′,N′′′}iron(III) |
title_sort | diammine{n-[2-(hydroxyimino)propionyl]-n′-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ(4)
n,n′,n′′,n′′′}iron(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588803/ https://www.ncbi.nlm.nih.gov/pubmed/23468768 http://dx.doi.org/10.1107/S160053681204826X |
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