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Diammine{N-[2-(hy­droxy­imino)­propion­yl]-N′-[2-(oxidoimino)­propion­yl]propane-1,3-diaminido-κ(4) N,N′,N′′,N′′′}iron(III)

In the title compound, [Fe(C(9)H(13)N(4)O(4))(NH(3))(2)], the Fe(III) atom, lying on a mirror plane, is coordinated by four N atoms of a triply deprotonated tetra­dentate N-[2-(hy­droxy­imino)­propion­yl]-N′-[2-(oxidoimino)­propion­yl]propane-1,3-diaminide ligand in the equatorial plane and two N at...

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Detalles Bibliográficos
Autores principales: Tomyn, Stefania, Haukka, Matti, Nedelkov, Ruslan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588803/
https://www.ncbi.nlm.nih.gov/pubmed/23468768
http://dx.doi.org/10.1107/S160053681204826X
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author Tomyn, Stefania
Haukka, Matti
Nedelkov, Ruslan
author_facet Tomyn, Stefania
Haukka, Matti
Nedelkov, Ruslan
author_sort Tomyn, Stefania
collection PubMed
description In the title compound, [Fe(C(9)H(13)N(4)O(4))(NH(3))(2)], the Fe(III) atom, lying on a mirror plane, is coordinated by four N atoms of a triply deprotonated tetra­dentate N-[2-(hy­droxy­imino)­propion­yl]-N′-[2-(oxidoimino)­propion­yl]propane-1,3-diaminide ligand in the equatorial plane and two N atoms of two ammonia mol­ecules at the axial positions in a distorted octa­hedral geometry. A short intra­molecular O—H⋯O hydrogen bond between the cis-disposed oxime O atoms stabilizes the pseudo-macrocyclic configuration of the ligand. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds into a three-dimensional network. The ligand has a mirror-plane symmetry. One of the methyl­ene groups of the propane bridge is disordered over two sets of sites with equal occupancy factors.
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spelling pubmed-35888032013-03-06 Diammine{N-[2-(hy­droxy­imino)­propion­yl]-N′-[2-(oxidoimino)­propion­yl]propane-1,3-diaminido-κ(4) N,N′,N′′,N′′′}iron(III) Tomyn, Stefania Haukka, Matti Nedelkov, Ruslan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(9)H(13)N(4)O(4))(NH(3))(2)], the Fe(III) atom, lying on a mirror plane, is coordinated by four N atoms of a triply deprotonated tetra­dentate N-[2-(hy­droxy­imino)­propion­yl]-N′-[2-(oxidoimino)­propion­yl]propane-1,3-diaminide ligand in the equatorial plane and two N atoms of two ammonia mol­ecules at the axial positions in a distorted octa­hedral geometry. A short intra­molecular O—H⋯O hydrogen bond between the cis-disposed oxime O atoms stabilizes the pseudo-macrocyclic configuration of the ligand. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds into a three-dimensional network. The ligand has a mirror-plane symmetry. One of the methyl­ene groups of the propane bridge is disordered over two sets of sites with equal occupancy factors. International Union of Crystallography 2012-11-30 /pmc/articles/PMC3588803/ /pubmed/23468768 http://dx.doi.org/10.1107/S160053681204826X Text en © Tomyn et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tomyn, Stefania
Haukka, Matti
Nedelkov, Ruslan
Diammine{N-[2-(hy­droxy­imino)­propion­yl]-N′-[2-(oxidoimino)­propion­yl]propane-1,3-diaminido-κ(4) N,N′,N′′,N′′′}iron(III)
title Diammine{N-[2-(hy­droxy­imino)­propion­yl]-N′-[2-(oxidoimino)­propion­yl]propane-1,3-diaminido-κ(4) N,N′,N′′,N′′′}iron(III)
title_full Diammine{N-[2-(hy­droxy­imino)­propion­yl]-N′-[2-(oxidoimino)­propion­yl]propane-1,3-diaminido-κ(4) N,N′,N′′,N′′′}iron(III)
title_fullStr Diammine{N-[2-(hy­droxy­imino)­propion­yl]-N′-[2-(oxidoimino)­propion­yl]propane-1,3-diaminido-κ(4) N,N′,N′′,N′′′}iron(III)
title_full_unstemmed Diammine{N-[2-(hy­droxy­imino)­propion­yl]-N′-[2-(oxidoimino)­propion­yl]propane-1,3-diaminido-κ(4) N,N′,N′′,N′′′}iron(III)
title_short Diammine{N-[2-(hy­droxy­imino)­propion­yl]-N′-[2-(oxidoimino)­propion­yl]propane-1,3-diaminido-κ(4) N,N′,N′′,N′′′}iron(III)
title_sort diammine{n-[2-(hy­droxy­imino)­propion­yl]-n′-[2-(oxidoimino)­propion­yl]propane-1,3-diaminido-κ(4) n,n′,n′′,n′′′}iron(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588803/
https://www.ncbi.nlm.nih.gov/pubmed/23468768
http://dx.doi.org/10.1107/S160053681204826X
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