Tris(1,10-phenanthroline-κ(2) N,N′)ruthenium(II) bis­(perchlorate)

The asymmetric unit of the title compound, [Ru(C(12)H(8)N(2))(3)](ClO(4))(2), contains one octahedrally coordinated Ru(II) cation of the ruthenium-phenanthroline complex and three differently occupied perchlorate anions: two, denoted A and B, are located on the twofold axis while another, denoted C,...

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Autores principales: Kozlowska, Mariana, Rodziewicz, Pawel, Brus, Diana Malgorzata, Czyrko, Justyna, Brzezinski, Krzysztof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588804/
https://www.ncbi.nlm.nih.gov/pubmed/23468769
http://dx.doi.org/10.1107/S1600536812048428
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author Kozlowska, Mariana
Rodziewicz, Pawel
Brus, Diana Malgorzata
Czyrko, Justyna
Brzezinski, Krzysztof
author_facet Kozlowska, Mariana
Rodziewicz, Pawel
Brus, Diana Malgorzata
Czyrko, Justyna
Brzezinski, Krzysztof
author_sort Kozlowska, Mariana
collection PubMed
description The asymmetric unit of the title compound, [Ru(C(12)H(8)N(2))(3)](ClO(4))(2), contains one octahedrally coordinated Ru(II) cation of the ruthenium-phenanthroline complex and three differently occupied perchlorate anions: two, denoted A and B, are located on the twofold axis while another, denoted C, is positioned in the proximity of the twofold screw axis. Perchlorate anions B and C are severely disordered. The occupancies of the two major conformers of anion B refined to 0.302 (6) and 0.198 (6). Perchlorate ion C was modeled in two alternate conformations which refined to occupancies of 0.552 (10) and 0.448 (10).
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spelling pubmed-35888042013-03-06 Tris(1,10-phenanthroline-κ(2) N,N′)ruthenium(II) bis­(perchlorate) Kozlowska, Mariana Rodziewicz, Pawel Brus, Diana Malgorzata Czyrko, Justyna Brzezinski, Krzysztof Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ru(C(12)H(8)N(2))(3)](ClO(4))(2), contains one octahedrally coordinated Ru(II) cation of the ruthenium-phenanthroline complex and three differently occupied perchlorate anions: two, denoted A and B, are located on the twofold axis while another, denoted C, is positioned in the proximity of the twofold screw axis. Perchlorate anions B and C are severely disordered. The occupancies of the two major conformers of anion B refined to 0.302 (6) and 0.198 (6). Perchlorate ion C was modeled in two alternate conformations which refined to occupancies of 0.552 (10) and 0.448 (10). International Union of Crystallography 2012-11-30 /pmc/articles/PMC3588804/ /pubmed/23468769 http://dx.doi.org/10.1107/S1600536812048428 Text en © Kozlowska et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kozlowska, Mariana
Rodziewicz, Pawel
Brus, Diana Malgorzata
Czyrko, Justyna
Brzezinski, Krzysztof
Tris(1,10-phenanthroline-κ(2) N,N′)ruthenium(II) bis­(perchlorate)
title Tris(1,10-phenanthroline-κ(2) N,N′)ruthenium(II) bis­(perchlorate)
title_full Tris(1,10-phenanthroline-κ(2) N,N′)ruthenium(II) bis­(perchlorate)
title_fullStr Tris(1,10-phenanthroline-κ(2) N,N′)ruthenium(II) bis­(perchlorate)
title_full_unstemmed Tris(1,10-phenanthroline-κ(2) N,N′)ruthenium(II) bis­(perchlorate)
title_short Tris(1,10-phenanthroline-κ(2) N,N′)ruthenium(II) bis­(perchlorate)
title_sort tris(1,10-phenanthroline-κ(2) n,n′)ruthenium(ii) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588804/
https://www.ncbi.nlm.nih.gov/pubmed/23468769
http://dx.doi.org/10.1107/S1600536812048428
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