Bis(μ-4,6-dimethyl­pyrimidine-2-thiol­ato)-κ(3) N,S:S;κ(3) S:N,S-bis­[(triphenyl­phosphane-κP)silver(I)]

The dinuclear title complex, [Ag(2)(C(6)H(7)N(2)S)(2)(C(18)H(15)P)(2)], comprises two inversion-related [Ag(C(6)H(7)N(2)S)(C(18)H(15)P)] units. The pyrimidine­thiol­ate anion acts both as a bridging and a chelating ligand. The Ag(I) ions are linked via two μ (2)-S donor atoms, which generate a stric...

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Detalles Bibliográficos
Autores principales: Wattanakanjana, Yupa, Pakawatchai, Chaveng, Kowittheeraphong, Sukanya, Nimthong, Ruthairat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588805/
https://www.ncbi.nlm.nih.gov/pubmed/23468770
http://dx.doi.org/10.1107/S1600536812048210
Descripción
Sumario:The dinuclear title complex, [Ag(2)(C(6)H(7)N(2)S)(2)(C(18)H(15)P)(2)], comprises two inversion-related [Ag(C(6)H(7)N(2)S)(C(18)H(15)P)] units. The pyrimidine­thiol­ate anion acts both as a bridging and a chelating ligand. The Ag(I) ions are linked via two μ (2)-S donor atoms, which generate a strictly planar Ag(2)S(2) core with an Ag⋯Ag separation of 2.9569 (4) Å. The Ag(I) ion presents a distorted tetra­hedral coordination geometry. In the crystal, weak C—H⋯N and C—H⋯S hydrogen bonds link the complex mol­ecules into a two-dimensional network parallel to (010).

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