Bis(μ-4,6-dimethyl­pyrimidine-2-thiol­ato)-κ(3) N,S:S;κ(3) S:N,S-bis­[(triphenyl­phosphane-κP)silver(I)]

The dinuclear title complex, [Ag(2)(C(6)H(7)N(2)S)(2)(C(18)H(15)P)(2)], comprises two inversion-related [Ag(C(6)H(7)N(2)S)(C(18)H(15)P)] units. The pyrimidine­thiol­ate anion acts both as a bridging and a chelating ligand. The Ag(I) ions are linked via two μ (2)-S donor atoms, which generate a stric...

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Autores principales: Wattanakanjana, Yupa, Pakawatchai, Chaveng, Kowittheeraphong, Sukanya, Nimthong, Ruthairat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588805/
https://www.ncbi.nlm.nih.gov/pubmed/23468770
http://dx.doi.org/10.1107/S1600536812048210
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author Wattanakanjana, Yupa
Pakawatchai, Chaveng
Kowittheeraphong, Sukanya
Nimthong, Ruthairat
author_facet Wattanakanjana, Yupa
Pakawatchai, Chaveng
Kowittheeraphong, Sukanya
Nimthong, Ruthairat
author_sort Wattanakanjana, Yupa
collection PubMed
description The dinuclear title complex, [Ag(2)(C(6)H(7)N(2)S)(2)(C(18)H(15)P)(2)], comprises two inversion-related [Ag(C(6)H(7)N(2)S)(C(18)H(15)P)] units. The pyrimidine­thiol­ate anion acts both as a bridging and a chelating ligand. The Ag(I) ions are linked via two μ (2)-S donor atoms, which generate a strictly planar Ag(2)S(2) core with an Ag⋯Ag separation of 2.9569 (4) Å. The Ag(I) ion presents a distorted tetra­hedral coordination geometry. In the crystal, weak C—H⋯N and C—H⋯S hydrogen bonds link the complex mol­ecules into a two-dimensional network parallel to (010).
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spelling pubmed-35888052013-03-06 Bis(μ-4,6-dimethyl­pyrimidine-2-thiol­ato)-κ(3) N,S:S;κ(3) S:N,S-bis­[(triphenyl­phosphane-κP)silver(I)] Wattanakanjana, Yupa Pakawatchai, Chaveng Kowittheeraphong, Sukanya Nimthong, Ruthairat Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title complex, [Ag(2)(C(6)H(7)N(2)S)(2)(C(18)H(15)P)(2)], comprises two inversion-related [Ag(C(6)H(7)N(2)S)(C(18)H(15)P)] units. The pyrimidine­thiol­ate anion acts both as a bridging and a chelating ligand. The Ag(I) ions are linked via two μ (2)-S donor atoms, which generate a strictly planar Ag(2)S(2) core with an Ag⋯Ag separation of 2.9569 (4) Å. The Ag(I) ion presents a distorted tetra­hedral coordination geometry. In the crystal, weak C—H⋯N and C—H⋯S hydrogen bonds link the complex mol­ecules into a two-dimensional network parallel to (010). International Union of Crystallography 2012-11-30 /pmc/articles/PMC3588805/ /pubmed/23468770 http://dx.doi.org/10.1107/S1600536812048210 Text en © Wattanakanjana et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wattanakanjana, Yupa
Pakawatchai, Chaveng
Kowittheeraphong, Sukanya
Nimthong, Ruthairat
Bis(μ-4,6-dimethyl­pyrimidine-2-thiol­ato)-κ(3) N,S:S;κ(3) S:N,S-bis­[(triphenyl­phosphane-κP)silver(I)]
title Bis(μ-4,6-dimethyl­pyrimidine-2-thiol­ato)-κ(3) N,S:S;κ(3) S:N,S-bis­[(triphenyl­phosphane-κP)silver(I)]
title_full Bis(μ-4,6-dimethyl­pyrimidine-2-thiol­ato)-κ(3) N,S:S;κ(3) S:N,S-bis­[(triphenyl­phosphane-κP)silver(I)]
title_fullStr Bis(μ-4,6-dimethyl­pyrimidine-2-thiol­ato)-κ(3) N,S:S;κ(3) S:N,S-bis­[(triphenyl­phosphane-κP)silver(I)]
title_full_unstemmed Bis(μ-4,6-dimethyl­pyrimidine-2-thiol­ato)-κ(3) N,S:S;κ(3) S:N,S-bis­[(triphenyl­phosphane-κP)silver(I)]
title_short Bis(μ-4,6-dimethyl­pyrimidine-2-thiol­ato)-κ(3) N,S:S;κ(3) S:N,S-bis­[(triphenyl­phosphane-κP)silver(I)]
title_sort bis(μ-4,6-dimethyl­pyrimidine-2-thiol­ato)-κ(3) n,s:s;κ(3) s:n,s-bis­[(triphenyl­phosphane-κp)silver(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588805/
https://www.ncbi.nlm.nih.gov/pubmed/23468770
http://dx.doi.org/10.1107/S1600536812048210
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