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4-Ferrocenyl-1-methyl-3-benzoylspiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline]
In the title compound, [Fe(C(5)H(5))(C(31)H(24)N(3)O)], the pyrrolidine ring adopts a twist conformation. The pyrrolidine ring is almost perpendicular to the indenoquinoxaline ring system, making a dihedral angle of 84.44 (5)°. The cyclopentadienyl rings of the ferrocene moiety adopt an eclipsed...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588807/ https://www.ncbi.nlm.nih.gov/pubmed/23468772 http://dx.doi.org/10.1107/S1600536812048349 |
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author | Vijayakumar, B. Sureshbabu, A. R. Gavaskar, D. Raghunathan, R. Velmurugan, D. |
author_facet | Vijayakumar, B. Sureshbabu, A. R. Gavaskar, D. Raghunathan, R. Velmurugan, D. |
author_sort | Vijayakumar, B. |
collection | PubMed |
description | In the title compound, [Fe(C(5)H(5))(C(31)H(24)N(3)O)], the pyrrolidine ring adopts a twist conformation. The pyrrolidine ring is almost perpendicular to the indenoquinoxaline ring system, making a dihedral angle of 84.44 (5)°. The cyclopentadienyl rings of the ferrocene moiety adopt an eclipsed conformation. The crystal packing features weak C—H⋯N and C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3588807 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35888072013-03-06 4-Ferrocenyl-1-methyl-3-benzoylspiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] Vijayakumar, B. Sureshbabu, A. R. Gavaskar, D. Raghunathan, R. Velmurugan, D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(31)H(24)N(3)O)], the pyrrolidine ring adopts a twist conformation. The pyrrolidine ring is almost perpendicular to the indenoquinoxaline ring system, making a dihedral angle of 84.44 (5)°. The cyclopentadienyl rings of the ferrocene moiety adopt an eclipsed conformation. The crystal packing features weak C—H⋯N and C—H⋯π interactions. International Union of Crystallography 2012-11-30 /pmc/articles/PMC3588807/ /pubmed/23468772 http://dx.doi.org/10.1107/S1600536812048349 Text en © Vijayakumar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Vijayakumar, B. Sureshbabu, A. R. Gavaskar, D. Raghunathan, R. Velmurugan, D. 4-Ferrocenyl-1-methyl-3-benzoylspiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] |
title | 4-Ferrocenyl-1-methyl-3-benzoylspiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] |
title_full | 4-Ferrocenyl-1-methyl-3-benzoylspiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] |
title_fullStr | 4-Ferrocenyl-1-methyl-3-benzoylspiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] |
title_full_unstemmed | 4-Ferrocenyl-1-methyl-3-benzoylspiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] |
title_short | 4-Ferrocenyl-1-methyl-3-benzoylspiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] |
title_sort | 4-ferrocenyl-1-methyl-3-benzoylspiro[pyrrolidine-2,11′-indeno[1,2-b]quinoxaline] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588807/ https://www.ncbi.nlm.nih.gov/pubmed/23468772 http://dx.doi.org/10.1107/S1600536812048349 |
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