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N′-[(E)-2-Hy­droxy-5-meth­oxy­benzyl­idene]-2-meth­oxy­benzohydrazide

The mol­ecule of the title compound, C(16)H(16)N(2)O(4), adopts an E conformation about the azomethine C=N double bond. The dihedral angle formed by the benzene rings is 18.88 (9)°. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond, which forms an S(6) ring. In the...

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Autores principales: Baharudin, M. Syukri., Taha, Muhammad, Ismail, Nor Hadiani, Shah, Syed Adnan Ali, Yousuf, Sammer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588809/
https://www.ncbi.nlm.nih.gov/pubmed/23468774
http://dx.doi.org/10.1107/S1600536812042389
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author Baharudin, M. Syukri.
Taha, Muhammad
Ismail, Nor Hadiani
Shah, Syed Adnan Ali
Yousuf, Sammer
author_facet Baharudin, M. Syukri.
Taha, Muhammad
Ismail, Nor Hadiani
Shah, Syed Adnan Ali
Yousuf, Sammer
author_sort Baharudin, M. Syukri.
collection PubMed
description The mol­ecule of the title compound, C(16)H(16)N(2)O(4), adopts an E conformation about the azomethine C=N double bond. The dihedral angle formed by the benzene rings is 18.88 (9)°. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond, which forms an S(6) ring. In the crystal, the mol­ecules are linked into chains parallel to [001] by N—H⋯O hydrogen bonds. The chains are further connected into a three-dimensional network by π–π stacking inter­actions with centroid–centroid distances of 3.6538 (10) and 3.8995 (11) Å.
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spelling pubmed-35888092013-03-06 N′-[(E)-2-Hy­droxy-5-meth­oxy­benzyl­idene]-2-meth­oxy­benzohydrazide Baharudin, M. Syukri. Taha, Muhammad Ismail, Nor Hadiani Shah, Syed Adnan Ali Yousuf, Sammer Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(16)H(16)N(2)O(4), adopts an E conformation about the azomethine C=N double bond. The dihedral angle formed by the benzene rings is 18.88 (9)°. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond, which forms an S(6) ring. In the crystal, the mol­ecules are linked into chains parallel to [001] by N—H⋯O hydrogen bonds. The chains are further connected into a three-dimensional network by π–π stacking inter­actions with centroid–centroid distances of 3.6538 (10) and 3.8995 (11) Å. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588809/ /pubmed/23468774 http://dx.doi.org/10.1107/S1600536812042389 Text en © Baharudin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Baharudin, M. Syukri.
Taha, Muhammad
Ismail, Nor Hadiani
Shah, Syed Adnan Ali
Yousuf, Sammer
N′-[(E)-2-Hy­droxy-5-meth­oxy­benzyl­idene]-2-meth­oxy­benzohydrazide
title N′-[(E)-2-Hy­droxy-5-meth­oxy­benzyl­idene]-2-meth­oxy­benzohydrazide
title_full N′-[(E)-2-Hy­droxy-5-meth­oxy­benzyl­idene]-2-meth­oxy­benzohydrazide
title_fullStr N′-[(E)-2-Hy­droxy-5-meth­oxy­benzyl­idene]-2-meth­oxy­benzohydrazide
title_full_unstemmed N′-[(E)-2-Hy­droxy-5-meth­oxy­benzyl­idene]-2-meth­oxy­benzohydrazide
title_short N′-[(E)-2-Hy­droxy-5-meth­oxy­benzyl­idene]-2-meth­oxy­benzohydrazide
title_sort n′-[(e)-2-hy­droxy-5-meth­oxy­benzyl­idene]-2-meth­oxy­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588809/
https://www.ncbi.nlm.nih.gov/pubmed/23468774
http://dx.doi.org/10.1107/S1600536812042389
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