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N′-[(E)-2-Hydroxy-5-methoxybenzylidene]-2-methoxybenzohydrazide
The molecule of the title compound, C(16)H(16)N(2)O(4), adopts an E conformation about the azomethine C=N double bond. The dihedral angle formed by the benzene rings is 18.88 (9)°. The molecular conformation is stabilized by an intramolecular O—H⋯N hydrogen bond, which forms an S(6) ring. In the...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588809/ https://www.ncbi.nlm.nih.gov/pubmed/23468774 http://dx.doi.org/10.1107/S1600536812042389 |
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author | Baharudin, M. Syukri. Taha, Muhammad Ismail, Nor Hadiani Shah, Syed Adnan Ali Yousuf, Sammer |
author_facet | Baharudin, M. Syukri. Taha, Muhammad Ismail, Nor Hadiani Shah, Syed Adnan Ali Yousuf, Sammer |
author_sort | Baharudin, M. Syukri. |
collection | PubMed |
description | The molecule of the title compound, C(16)H(16)N(2)O(4), adopts an E conformation about the azomethine C=N double bond. The dihedral angle formed by the benzene rings is 18.88 (9)°. The molecular conformation is stabilized by an intramolecular O—H⋯N hydrogen bond, which forms an S(6) ring. In the crystal, the molecules are linked into chains parallel to [001] by N—H⋯O hydrogen bonds. The chains are further connected into a three-dimensional network by π–π stacking interactions with centroid–centroid distances of 3.6538 (10) and 3.8995 (11) Å. |
format | Online Article Text |
id | pubmed-3588809 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35888092013-03-06 N′-[(E)-2-Hydroxy-5-methoxybenzylidene]-2-methoxybenzohydrazide Baharudin, M. Syukri. Taha, Muhammad Ismail, Nor Hadiani Shah, Syed Adnan Ali Yousuf, Sammer Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(16)H(16)N(2)O(4), adopts an E conformation about the azomethine C=N double bond. The dihedral angle formed by the benzene rings is 18.88 (9)°. The molecular conformation is stabilized by an intramolecular O—H⋯N hydrogen bond, which forms an S(6) ring. In the crystal, the molecules are linked into chains parallel to [001] by N—H⋯O hydrogen bonds. The chains are further connected into a three-dimensional network by π–π stacking interactions with centroid–centroid distances of 3.6538 (10) and 3.8995 (11) Å. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588809/ /pubmed/23468774 http://dx.doi.org/10.1107/S1600536812042389 Text en © Baharudin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Baharudin, M. Syukri. Taha, Muhammad Ismail, Nor Hadiani Shah, Syed Adnan Ali Yousuf, Sammer N′-[(E)-2-Hydroxy-5-methoxybenzylidene]-2-methoxybenzohydrazide |
title |
N′-[(E)-2-Hydroxy-5-methoxybenzylidene]-2-methoxybenzohydrazide |
title_full |
N′-[(E)-2-Hydroxy-5-methoxybenzylidene]-2-methoxybenzohydrazide |
title_fullStr |
N′-[(E)-2-Hydroxy-5-methoxybenzylidene]-2-methoxybenzohydrazide |
title_full_unstemmed |
N′-[(E)-2-Hydroxy-5-methoxybenzylidene]-2-methoxybenzohydrazide |
title_short |
N′-[(E)-2-Hydroxy-5-methoxybenzylidene]-2-methoxybenzohydrazide |
title_sort | n′-[(e)-2-hydroxy-5-methoxybenzylidene]-2-methoxybenzohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588809/ https://www.ncbi.nlm.nih.gov/pubmed/23468774 http://dx.doi.org/10.1107/S1600536812042389 |
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