Bis(adeninium) bis­(hydrogensulfate) sulfate

The title compound, 2C(5)H(7)N(5) (2+)·2HSO(4) (−)·SO(4) (2−), was synthesized from adenine and sulfuric acid. The asymmetric unit contains two diprotonated adeninium cations, two bis­ulfate anions and one sulfate anion. The crystal structure is stabilized by classical N—H⋯O and O—H⋯O hydrogen bonds...

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Detalles Bibliográficos
Autores principales: Guenifa, Fatiha, Bendjeddou, Lamia, Cherouana, Aouatef, Dahaoui, Slimane, Lecomte, Claude
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588817/
https://www.ncbi.nlm.nih.gov/pubmed/23468782
http://dx.doi.org/10.1107/S1600536812044728
Descripción
Sumario:The title compound, 2C(5)H(7)N(5) (2+)·2HSO(4) (−)·SO(4) (2−), was synthesized from adenine and sulfuric acid. The asymmetric unit contains two diprotonated adeninium cations, two bis­ulfate anions and one sulfate anion. The crystal structure is stabilized by classical N—H⋯O and O—H⋯O hydrogen bonds, and weak C—H⋯O and C—H⋯N hydrogen bonds, generating a three-dimensional network.

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