(2E)-1-Phenyl-2-[1-(2-phenyl­prop-2-en-1-yl)pyrrolidin-2-yl­idene]ethanone

The title compound, C(21)H(21)NO, is a vinyl­ogous amide (enaminone) produced by reaction of 1-(2-phenyl­prop-2-en-1-yl)pyrrolidine-2-thione with phenacyl bromide. In the mol­ecule, the phenyl rings are twisted from the mean plane of the pyrrolidine ring by 11.2 (1) and 67.3 (1)°. In the crystal, we...

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Detalles Bibliográficos
Autores principales: Madeley, Lee G., Morgans, Garreth L., Lemmerer, Andreas, Michael, Joseph P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588828/
https://www.ncbi.nlm.nih.gov/pubmed/23468793
http://dx.doi.org/10.1107/S1600536812044443
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author Madeley, Lee G.
Morgans, Garreth L.
Lemmerer, Andreas
Michael, Joseph P.
author_facet Madeley, Lee G.
Morgans, Garreth L.
Lemmerer, Andreas
Michael, Joseph P.
author_sort Madeley, Lee G.
collection PubMed
description The title compound, C(21)H(21)NO, is a vinyl­ogous amide (enaminone) produced by reaction of 1-(2-phenyl­prop-2-en-1-yl)pyrrolidine-2-thione with phenacyl bromide. In the mol­ecule, the phenyl rings are twisted from the mean plane of the pyrrolidine ring by 11.2 (1) and 67.3 (1)°. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules related by translation along the b axis into chains.
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spelling pubmed-35888282013-03-06 (2E)-1-Phenyl-2-[1-(2-phenyl­prop-2-en-1-yl)pyrrolidin-2-yl­idene]ethanone Madeley, Lee G. Morgans, Garreth L. Lemmerer, Andreas Michael, Joseph P. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(21)NO, is a vinyl­ogous amide (enaminone) produced by reaction of 1-(2-phenyl­prop-2-en-1-yl)pyrrolidine-2-thione with phenacyl bromide. In the mol­ecule, the phenyl rings are twisted from the mean plane of the pyrrolidine ring by 11.2 (1) and 67.3 (1)°. In the crystal, weak C—H⋯O hydrogen bonds link the mol­ecules related by translation along the b axis into chains. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588828/ /pubmed/23468793 http://dx.doi.org/10.1107/S1600536812044443 Text en © Madeley et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Madeley, Lee G.
Morgans, Garreth L.
Lemmerer, Andreas
Michael, Joseph P.
(2E)-1-Phenyl-2-[1-(2-phenyl­prop-2-en-1-yl)pyrrolidin-2-yl­idene]ethanone
title (2E)-1-Phenyl-2-[1-(2-phenyl­prop-2-en-1-yl)pyrrolidin-2-yl­idene]ethanone
title_full (2E)-1-Phenyl-2-[1-(2-phenyl­prop-2-en-1-yl)pyrrolidin-2-yl­idene]ethanone
title_fullStr (2E)-1-Phenyl-2-[1-(2-phenyl­prop-2-en-1-yl)pyrrolidin-2-yl­idene]ethanone
title_full_unstemmed (2E)-1-Phenyl-2-[1-(2-phenyl­prop-2-en-1-yl)pyrrolidin-2-yl­idene]ethanone
title_short (2E)-1-Phenyl-2-[1-(2-phenyl­prop-2-en-1-yl)pyrrolidin-2-yl­idene]ethanone
title_sort (2e)-1-phenyl-2-[1-(2-phenyl­prop-2-en-1-yl)pyrrolidin-2-yl­idene]ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588828/
https://www.ncbi.nlm.nih.gov/pubmed/23468793
http://dx.doi.org/10.1107/S1600536812044443
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