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Tetra­butyl­ammonium 2-[2,5-dimethyl-3-(4-nitro­phen­yl)-2,3-dihydro-1,2,4-oxadiazo­lium-4-yl]nona­hydro-closo-deca­borate

The title ionic compound, C(16)H(36)N(+)·C(10)H(20)B(10)N(3)O(3) (−), consists of a tetra­butyl­ammonium cation and a closo-deca­borate cluster anion, which is bound to the substituted 2,3-dihydro-1,2,4-oxadiazole ring through a B—N bond [1.540 (2) Å]. The distances between connected B atoms in the...

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Autores principales: Mindich, Aleksey L., Pavlishchuk, Anna V., Bokach, Nadezhda A., Starova, Galina L., Zhizhin, Konstantin Yu.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588831/
https://www.ncbi.nlm.nih.gov/pubmed/23468796
http://dx.doi.org/10.1107/S1600536812044984
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author Mindich, Aleksey L.
Pavlishchuk, Anna V.
Bokach, Nadezhda A.
Starova, Galina L.
Zhizhin, Konstantin Yu.
author_facet Mindich, Aleksey L.
Pavlishchuk, Anna V.
Bokach, Nadezhda A.
Starova, Galina L.
Zhizhin, Konstantin Yu.
author_sort Mindich, Aleksey L.
collection PubMed
description The title ionic compound, C(16)H(36)N(+)·C(10)H(20)B(10)N(3)O(3) (−), consists of a tetra­butyl­ammonium cation and a closo-deca­borate cluster anion, which is bound to the substituted 2,3-dihydro-1,2,4-oxadiazole ring through a B—N bond [1.540 (2) Å]. The distances between connected B atoms in the deca­borate cluster range from 1.689 (2) to 1.844 (2) Å. The 2,3-dihydro-1,2,4-oxadiazole ring adopts an envelope conformation with the N atom as the flap atom.
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spelling pubmed-35888312013-03-06 Tetra­butyl­ammonium 2-[2,5-dimethyl-3-(4-nitro­phen­yl)-2,3-dihydro-1,2,4-oxadiazo­lium-4-yl]nona­hydro-closo-deca­borate Mindich, Aleksey L. Pavlishchuk, Anna V. Bokach, Nadezhda A. Starova, Galina L. Zhizhin, Konstantin Yu. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title ionic compound, C(16)H(36)N(+)·C(10)H(20)B(10)N(3)O(3) (−), consists of a tetra­butyl­ammonium cation and a closo-deca­borate cluster anion, which is bound to the substituted 2,3-dihydro-1,2,4-oxadiazole ring through a B—N bond [1.540 (2) Å]. The distances between connected B atoms in the deca­borate cluster range from 1.689 (2) to 1.844 (2) Å. The 2,3-dihydro-1,2,4-oxadiazole ring adopts an envelope conformation with the N atom as the flap atom. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588831/ /pubmed/23468796 http://dx.doi.org/10.1107/S1600536812044984 Text en © Mindich et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mindich, Aleksey L.
Pavlishchuk, Anna V.
Bokach, Nadezhda A.
Starova, Galina L.
Zhizhin, Konstantin Yu.
Tetra­butyl­ammonium 2-[2,5-dimethyl-3-(4-nitro­phen­yl)-2,3-dihydro-1,2,4-oxadiazo­lium-4-yl]nona­hydro-closo-deca­borate
title Tetra­butyl­ammonium 2-[2,5-dimethyl-3-(4-nitro­phen­yl)-2,3-dihydro-1,2,4-oxadiazo­lium-4-yl]nona­hydro-closo-deca­borate
title_full Tetra­butyl­ammonium 2-[2,5-dimethyl-3-(4-nitro­phen­yl)-2,3-dihydro-1,2,4-oxadiazo­lium-4-yl]nona­hydro-closo-deca­borate
title_fullStr Tetra­butyl­ammonium 2-[2,5-dimethyl-3-(4-nitro­phen­yl)-2,3-dihydro-1,2,4-oxadiazo­lium-4-yl]nona­hydro-closo-deca­borate
title_full_unstemmed Tetra­butyl­ammonium 2-[2,5-dimethyl-3-(4-nitro­phen­yl)-2,3-dihydro-1,2,4-oxadiazo­lium-4-yl]nona­hydro-closo-deca­borate
title_short Tetra­butyl­ammonium 2-[2,5-dimethyl-3-(4-nitro­phen­yl)-2,3-dihydro-1,2,4-oxadiazo­lium-4-yl]nona­hydro-closo-deca­borate
title_sort tetra­butyl­ammonium 2-[2,5-dimethyl-3-(4-nitro­phen­yl)-2,3-dihydro-1,2,4-oxadiazo­lium-4-yl]nona­hydro-closo-deca­borate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588831/
https://www.ncbi.nlm.nih.gov/pubmed/23468796
http://dx.doi.org/10.1107/S1600536812044984
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