1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride dimethyl­formamide monosolvate

In the imidazolium cation of the title compound, C(19)H(19)N(4)O(2) (+)·Cl(−)·C(3)H(7)NO, the dihedral angles between the imidazole ring and the phenyl rings are 85.86 (4) and 70.26 (5)°. In the crystal, N—H⋯Cl hydrogen bonds link the imdiazo­lium cations and chloride anions into zigzag chains along...

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Detalles Bibliográficos
Autores principales: Lee, Hon Man, Zeng, Jing-Yao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588832/
https://www.ncbi.nlm.nih.gov/pubmed/23468797
http://dx.doi.org/10.1107/S1600536812045059
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author Lee, Hon Man
Zeng, Jing-Yao
author_facet Lee, Hon Man
Zeng, Jing-Yao
author_sort Lee, Hon Man
collection PubMed
description In the imidazolium cation of the title compound, C(19)H(19)N(4)O(2) (+)·Cl(−)·C(3)H(7)NO, the dihedral angles between the imidazole ring and the phenyl rings are 85.86 (4) and 70.26 (5)°. In the crystal, N—H⋯Cl hydrogen bonds link the imdiazo­lium cations and chloride anions into zigzag chains along [110] and together with C—H⋯Cl and C—H⋯O hydrogen bonds, which involve also the dimethyl­formamide solvent mol­ecule, form a two-dimensional network extending across the ab plane.
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spelling pubmed-35888322013-03-06 1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride dimethyl­formamide monosolvate Lee, Hon Man Zeng, Jing-Yao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the imidazolium cation of the title compound, C(19)H(19)N(4)O(2) (+)·Cl(−)·C(3)H(7)NO, the dihedral angles between the imidazole ring and the phenyl rings are 85.86 (4) and 70.26 (5)°. In the crystal, N—H⋯Cl hydrogen bonds link the imdiazo­lium cations and chloride anions into zigzag chains along [110] and together with C—H⋯Cl and C—H⋯O hydrogen bonds, which involve also the dimethyl­formamide solvent mol­ecule, form a two-dimensional network extending across the ab plane. International Union of Crystallography 2012-11-03 /pmc/articles/PMC3588832/ /pubmed/23468797 http://dx.doi.org/10.1107/S1600536812045059 Text en © Lee and Zeng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lee, Hon Man
Zeng, Jing-Yao
1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride dimethyl­formamide monosolvate
title 1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride dimethyl­formamide monosolvate
title_full 1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride dimethyl­formamide monosolvate
title_fullStr 1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride dimethyl­formamide monosolvate
title_full_unstemmed 1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride dimethyl­formamide monosolvate
title_short 1,3-Bis(2-anilino-2-oxoeth­yl)-1H-imidazol-3-ium chloride dimethyl­formamide monosolvate
title_sort 1,3-bis(2-anilino-2-oxoeth­yl)-1h-imidazol-3-ium chloride dimethyl­formamide monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588832/
https://www.ncbi.nlm.nih.gov/pubmed/23468797
http://dx.doi.org/10.1107/S1600536812045059
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