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17-Hy­droxy-1,8-dimethyl-17-aza­penta­cyclo­[6.6.5.0(2,7).0(9,14).0(15,19)]nona­deca-2,4,6,9(14),10,12-hexa­ene-16,18-dione

In the title compound, C(20)H(17)NO(3) (alternative name: N-hy­droxy-9,10-dimethyl-9,10-ethano­anthracene-11,12-dicarboximide), the rigid ethano­anthracene-dicarboximide moiety has a roof-shaped geometry, the inter­planar angle between the two terminal phenyl rings being 124.9 (6)°. In the crystal,...

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Detalles Bibliográficos
Autores principales: Miroslaw, Barbara, Koziol, Anna E., Pakosinska-Parys, Magdalena, Struga, Marta
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588838/
https://www.ncbi.nlm.nih.gov/pubmed/23468803
http://dx.doi.org/10.1107/S1600536812045151
Descripción
Sumario:In the title compound, C(20)H(17)NO(3) (alternative name: N-hy­droxy-9,10-dimethyl-9,10-ethano­anthracene-11,12-dicarboximide), the rigid ethano­anthracene-dicarboximide moiety has a roof-shaped geometry, the inter­planar angle between the two terminal phenyl rings being 124.9 (6)°. In the crystal, mol­ecules are linked via O—H⋯O hydrogen bonds, forming chains along [010]. C—H⋯O and C—H⋯π inter­actions link adjacent chains, leading to the formation of a three-dimensional structure.