2,3-Dihydro-1H-pyrrolo­[1,2-a]indole-9-carbonitrile

The asymmetric unit of the title compound, C(12)H(10)N(2), which may serve as a model for mitosenes, contains two independent mol­ecules. The conformation of the five-membered rings in both molecules is envelope, with the central CH(2)—CH(2)—CH(2) C atom at the flap in each case. In the crystal, the...

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Detalles Bibliográficos
Autores principales: Madeley, Lee G., Lemmerer, Andreas, Michael, Joseph P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588846/
https://www.ncbi.nlm.nih.gov/pubmed/23468811
http://dx.doi.org/10.1107/S1600536812045345
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author Madeley, Lee G.
Lemmerer, Andreas
Michael, Joseph P.
author_facet Madeley, Lee G.
Lemmerer, Andreas
Michael, Joseph P.
author_sort Madeley, Lee G.
collection PubMed
description The asymmetric unit of the title compound, C(12)H(10)N(2), which may serve as a model for mitosenes, contains two independent mol­ecules. The conformation of the five-membered rings in both molecules is envelope, with the central CH(2)—CH(2)—CH(2) C atom at the flap in each case. In the crystal, they inter­act by a combination of weak C—H⋯N and π–π inter­actions [centroid–centroid distances = 3.616 (1) and 3.499 (1) Å] and C—H⋯π contacts.
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spelling pubmed-35888462013-03-06 2,3-Dihydro-1H-pyrrolo­[1,2-a]indole-9-carbonitrile Madeley, Lee G. Lemmerer, Andreas Michael, Joseph P. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(12)H(10)N(2), which may serve as a model for mitosenes, contains two independent mol­ecules. The conformation of the five-membered rings in both molecules is envelope, with the central CH(2)—CH(2)—CH(2) C atom at the flap in each case. In the crystal, they inter­act by a combination of weak C—H⋯N and π–π inter­actions [centroid–centroid distances = 3.616 (1) and 3.499 (1) Å] and C—H⋯π contacts. International Union of Crystallography 2012-11-10 /pmc/articles/PMC3588846/ /pubmed/23468811 http://dx.doi.org/10.1107/S1600536812045345 Text en © Madeley et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Madeley, Lee G.
Lemmerer, Andreas
Michael, Joseph P.
2,3-Dihydro-1H-pyrrolo­[1,2-a]indole-9-carbonitrile
title 2,3-Dihydro-1H-pyrrolo­[1,2-a]indole-9-carbonitrile
title_full 2,3-Dihydro-1H-pyrrolo­[1,2-a]indole-9-carbonitrile
title_fullStr 2,3-Dihydro-1H-pyrrolo­[1,2-a]indole-9-carbonitrile
title_full_unstemmed 2,3-Dihydro-1H-pyrrolo­[1,2-a]indole-9-carbonitrile
title_short 2,3-Dihydro-1H-pyrrolo­[1,2-a]indole-9-carbonitrile
title_sort 2,3-dihydro-1h-pyrrolo­[1,2-a]indole-9-carbonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588846/
https://www.ncbi.nlm.nih.gov/pubmed/23468811
http://dx.doi.org/10.1107/S1600536812045345
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