5-[(E)-Meth­oxy(phen­yl)methyl­idene]-1,3,4-triphenyl-4,5-dihydro-1H-1,2,4-triazole

In the title compound, C(28)H(23)N(3)O, the 1,2,4-triazole ring deviates slightly from planarity adopting a (N3) T (C2) conformation which is distorted towards an E (C2) conformation. The plane around the ethyl­ene unit makes a dihedral angle of 17.32 (11)° with the mean plane [r.m.s. deviation = 0....

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Detalles Bibliográficos
Autores principales: Maji, Biplab, Berionni, Guillaume, Mayr, Herbert, Mayer, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588847/
https://www.ncbi.nlm.nih.gov/pubmed/23468812
http://dx.doi.org/10.1107/S1600536812045692
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author Maji, Biplab
Berionni, Guillaume
Mayr, Herbert
Mayer, Peter
author_facet Maji, Biplab
Berionni, Guillaume
Mayr, Herbert
Mayer, Peter
author_sort Maji, Biplab
collection PubMed
description In the title compound, C(28)H(23)N(3)O, the 1,2,4-triazole ring deviates slightly from planarity adopting a (N3) T (C2) conformation which is distorted towards an E (C2) conformation. The plane around the ethyl­ene unit makes a dihedral angle of 17.32 (11)° with the mean plane [r.m.s. deviation = 0.036 (1) Å] of the 1,2,4-triazole fragment. The dihedral angles between the four phenyl rings and the 1,2,4-triazole ring are 31.01 (10), 49.01 (8), 78.55 (6) and 41.51 (9)°. In the crystal, mol­ecules are linked along [100] by weak C—H⋯O hydrogen bonds.
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spelling pubmed-35888472013-03-06 5-[(E)-Meth­oxy(phen­yl)methyl­idene]-1,3,4-triphenyl-4,5-dihydro-1H-1,2,4-triazole Maji, Biplab Berionni, Guillaume Mayr, Herbert Mayer, Peter Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(23)N(3)O, the 1,2,4-triazole ring deviates slightly from planarity adopting a (N3) T (C2) conformation which is distorted towards an E (C2) conformation. The plane around the ethyl­ene unit makes a dihedral angle of 17.32 (11)° with the mean plane [r.m.s. deviation = 0.036 (1) Å] of the 1,2,4-triazole fragment. The dihedral angles between the four phenyl rings and the 1,2,4-triazole ring are 31.01 (10), 49.01 (8), 78.55 (6) and 41.51 (9)°. In the crystal, mol­ecules are linked along [100] by weak C—H⋯O hydrogen bonds. International Union of Crystallography 2012-11-10 /pmc/articles/PMC3588847/ /pubmed/23468812 http://dx.doi.org/10.1107/S1600536812045692 Text en © Maji et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Maji, Biplab
Berionni, Guillaume
Mayr, Herbert
Mayer, Peter
5-[(E)-Meth­oxy(phen­yl)methyl­idene]-1,3,4-triphenyl-4,5-dihydro-1H-1,2,4-triazole
title 5-[(E)-Meth­oxy(phen­yl)methyl­idene]-1,3,4-triphenyl-4,5-dihydro-1H-1,2,4-triazole
title_full 5-[(E)-Meth­oxy(phen­yl)methyl­idene]-1,3,4-triphenyl-4,5-dihydro-1H-1,2,4-triazole
title_fullStr 5-[(E)-Meth­oxy(phen­yl)methyl­idene]-1,3,4-triphenyl-4,5-dihydro-1H-1,2,4-triazole
title_full_unstemmed 5-[(E)-Meth­oxy(phen­yl)methyl­idene]-1,3,4-triphenyl-4,5-dihydro-1H-1,2,4-triazole
title_short 5-[(E)-Meth­oxy(phen­yl)methyl­idene]-1,3,4-triphenyl-4,5-dihydro-1H-1,2,4-triazole
title_sort 5-[(e)-meth­oxy(phen­yl)methyl­idene]-1,3,4-triphenyl-4,5-dihydro-1h-1,2,4-triazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588847/
https://www.ncbi.nlm.nih.gov/pubmed/23468812
http://dx.doi.org/10.1107/S1600536812045692
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AT mayrherbert 5emethoxyphenylmethylidene134triphenyl45dihydro1h124triazole
AT mayerpeter 5emethoxyphenylmethylidene134triphenyl45dihydro1h124triazole

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