2-Amino-5-methyl­pyridinium trifluoro­acetate

In the title salt, C(6)H(9)N(2) (+)·C(2)F(3)O(2) (−), the F atoms of the anion are disordered over two sets of sites, with refined occupancies in a ratio of 0.505 (17):0.495 (17). In the crystal, cations and anions are linked via N—H⋯O hydrogen bonds, forming R (2) (2)(8) ring motifs. The ionic unit...

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Autores principales: Thanigaimani, Kaliyaperumal, Farhadikoutenaei, Abbas, Khalib, Nuridayanti Che, Arshad, Suhana, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588927/
https://www.ncbi.nlm.nih.gov/pubmed/23476163
http://dx.doi.org/10.1107/S1600536812045291
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author Thanigaimani, Kaliyaperumal
Farhadikoutenaei, Abbas
Khalib, Nuridayanti Che
Arshad, Suhana
Razak, Ibrahim Abdul
author_facet Thanigaimani, Kaliyaperumal
Farhadikoutenaei, Abbas
Khalib, Nuridayanti Che
Arshad, Suhana
Razak, Ibrahim Abdul
author_sort Thanigaimani, Kaliyaperumal
collection PubMed
description In the title salt, C(6)H(9)N(2) (+)·C(2)F(3)O(2) (−), the F atoms of the anion are disordered over two sets of sites, with refined occupancies in a ratio of 0.505 (17):0.495 (17). In the crystal, cations and anions are linked via N—H⋯O hydrogen bonds, forming R (2) (2)(8) ring motifs. The ionic units are linked into a two-dimensional network parallel to (100) by N—H⋯O and weak C—H⋯O hydrogen bonds. The crystal structure is further stabilized by weak C—H⋯F hydrogen bonds, resulting in a three-dimensional network.
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spelling pubmed-35889272013-03-08 2-Amino-5-methyl­pyridinium trifluoro­acetate Thanigaimani, Kaliyaperumal Farhadikoutenaei, Abbas Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(6)H(9)N(2) (+)·C(2)F(3)O(2) (−), the F atoms of the anion are disordered over two sets of sites, with refined occupancies in a ratio of 0.505 (17):0.495 (17). In the crystal, cations and anions are linked via N—H⋯O hydrogen bonds, forming R (2) (2)(8) ring motifs. The ionic units are linked into a two-dimensional network parallel to (100) by N—H⋯O and weak C—H⋯O hydrogen bonds. The crystal structure is further stabilized by weak C—H⋯F hydrogen bonds, resulting in a three-dimensional network. International Union of Crystallography 2012-11-10 /pmc/articles/PMC3588927/ /pubmed/23476163 http://dx.doi.org/10.1107/S1600536812045291 Text en © Thanigaimani et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thanigaimani, Kaliyaperumal
Farhadikoutenaei, Abbas
Khalib, Nuridayanti Che
Arshad, Suhana
Razak, Ibrahim Abdul
2-Amino-5-methyl­pyridinium trifluoro­acetate
title 2-Amino-5-methyl­pyridinium trifluoro­acetate
title_full 2-Amino-5-methyl­pyridinium trifluoro­acetate
title_fullStr 2-Amino-5-methyl­pyridinium trifluoro­acetate
title_full_unstemmed 2-Amino-5-methyl­pyridinium trifluoro­acetate
title_short 2-Amino-5-methyl­pyridinium trifluoro­acetate
title_sort 2-amino-5-methyl­pyridinium trifluoro­acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588927/
https://www.ncbi.nlm.nih.gov/pubmed/23476163
http://dx.doi.org/10.1107/S1600536812045291
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AT arshadsuhana 2amino5methylpyridiniumtrifluoroacetate
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