(5S,11aS)-5-Hydro­per­oxy-1,5,11,11a-tetra­hydro­[1]benzothieno[3,2-f]indol­izin-3(2H)-one

The absolute configuration of the title compound, C(14)H(13)NO(3)S, was assigned from the synthesis and confirmed by the structure determination. The central six-membered ring of the indolizine moiety adopts an envelope conformation, with the greatest deviation from the mean plane of the ring being...

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Detalles Bibliográficos
Autores principales: Vrábel, Viktor, Švorc, Ľubomír, Marchalín, Štefan, Šafář, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588932/
https://www.ncbi.nlm.nih.gov/pubmed/23476168
http://dx.doi.org/10.1107/S1600536812045394
Descripción
Sumario:The absolute configuration of the title compound, C(14)H(13)NO(3)S, was assigned from the synthesis and confirmed by the structure determination. The central six-membered ring of the indolizine moiety adopts an envelope conformation, with the greatest deviation from the mean plane of the ring being 0.661 (2) Å for the bridgehead C atom. The benzothiene ring attached to the indolizine ring system is planar to within 0.008 (2) Å. In the crystal, mol­ecules form chains parallel to the b axis via O—H⋯O hydrogen bonds.

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