9-(5-Bromo-1H-indol-3-yl)-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione dimethyl sulfoxide monosolvate

In the title compound, C(21)H(19)BrN(2)O(2)·C(2)H(6)OS, the indole ring system is essentially planar, with a maximum deviation of 0.050 (3) Å for the non-bridgehead C atom adjacent to the N atom. The two cyclo­hex-2-enone rings adopt half-chair conformations. An intra­molecular C—H⋯O hydrogen bond o...

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Detalles Bibliográficos
Autores principales: El-Khouly, Ahmed, Öztürk Yildirim, Sema, Butcher, Ray J., Şimsek, Rahime, Şafak, Cihat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588939/
https://www.ncbi.nlm.nih.gov/pubmed/23476175
http://dx.doi.org/10.1107/S1600536812045886
Descripción
Sumario:In the title compound, C(21)H(19)BrN(2)O(2)·C(2)H(6)OS, the indole ring system is essentially planar, with a maximum deviation of 0.050 (3) Å for the non-bridgehead C atom adjacent to the N atom. The two cyclo­hex-2-enone rings adopt half-chair conformations. An intra­molecular C—H⋯O hydrogen bond occurs. The solvent mol­ecule exhibits minor disorder of the S atom [site occupancies = 0.8153 (16) and 0.1847 (18)]. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds, forming layers parallel to the bc plane.

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