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4′-Methyl-1H-14′,19′-dioxa-4′-aza­spiro­[indole-3,5′-tetra­cyclo­[18.4.0.0(2,6).0(8,13)]tetra­cosa­ne]-1′(24′),8′,10′,12′,20′,22′-hexa­ene-2,7′(3H)-dione

In the title compound, C(29)H(28)N(2)O(4), the indoline ring system is essentially planar, with a maximum deviation of 0.027 (2) Å; the carbonyl O atom lies 0.102 (1) Å out of the least-squares plane of the indole ring. The pyrrolidine ring adopts a C-envelope conformation, with a C atom displaced b...

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Detalles Bibliográficos
Autores principales: Narayanan, Sibi, Srinivasan, Thothadri, Purushothaman, Santhanagopalan, Raghunathan, Raghavachary, Velmurugan, Devadasan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588945/
https://www.ncbi.nlm.nih.gov/pubmed/23476181
http://dx.doi.org/10.1107/S1600536812046132
Descripción
Sumario:In the title compound, C(29)H(28)N(2)O(4), the indoline ring system is essentially planar, with a maximum deviation of 0.027 (2) Å; the carbonyl O atom lies 0.102 (1) Å out of the least-squares plane of the indole ring. The pyrrolidine ring adopts a C-envelope conformation, with a C atom displaced by 0.643 (2) Å from the mean plane formed by the remaining ring atoms. The pyrrolidine ring makes a dihedral angle of 86.1 (8)° with the indoline ring system. In the crystal, N—H⋯O hydrogen bonds result in the formation of cyclic centrosymmetric dimers [R (2) (2)(8)]. C—H⋯π inter­actions also occur, leading to a chain along the b-axis direction. There is a rather weak π–π electron inter­action between the pyrrazole and benzene rings, with a centroid–centroid distance of 3.765 (1) Å.